What does translational energy have to do with entropy change?

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SUMMARY

The discussion centers on the relationship between translational energy and entropy change in an isothermal system. The translational energy of gas is quantified by the formula 3/2NkT, where N represents the number of molecules, k is Boltzmann's constant, and T is temperature. The change in entropy, expressed as (delta)S = (integral from 1 to 2) dU/T + (integral from 1 to 2) PdV/T, simplifies to NRln(v2/v1) when the internal energy U equals zero. This simplification occurs by applying the ideal gas law, PV = NRT, to express pressure in terms of volume and temperature.

PREREQUISITES
  • Understanding of the ideal gas law (PV = NRT)
  • Familiarity with Boltzmann's constant (k)
  • Knowledge of entropy and its mathematical representation
  • Basic principles of thermodynamics, particularly isothermal processes
NEXT STEPS
  • Study the derivation of the entropy formula for isothermal processes
  • Explore the implications of translational energy in thermodynamic systems
  • Learn about the relationship between pressure, volume, and temperature in ideal gases
  • Investigate the role of Boltzmann's constant in statistical mechanics
USEFUL FOR

Students of thermodynamics, physicists, and anyone studying the principles of entropy and energy in gas systems will benefit from this discussion.

giggidygigg
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I know that the translational energy of gas can be represented by
3/2NkT
where N = number of molecules, k = boltzmann's constant, T = temperature

my textbook says that the change in entropy is
(delta)S = (integral from 1 to 2) dS = (integral from 1 to 2) dU/T + (integral from 1 to 2) PdV/T = NRln(v2/v1)

i know that since U = 0 in an isothermal system, dU/T term gets canceled and the PdV/T term is left, but i don't understand how we get NRln(v2/v1) from it

i also don't know how translational energy comes into place.

much help needed!
 
Science news on Phys.org
Try using the ideal gas law PV = NRT to put the P/T in terms of V. Hope this helps.
 

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