What happens when water is heated above its critical temperature?

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Discussion Overview

The discussion centers on the behavior of water when heated above its critical temperature of 374°C (705.2°F) within a hermetically sealed, non-deformable metal container. Participants explore the implications of this scenario regarding phase changes and the properties of water in supercritical conditions.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification

Main Points Raised

  • One participant questions whether water will become steam when heated above its critical temperature, given that the container is fully filled with water, which is denser than steam.
  • Another participant explains that above the critical temperature, water exists as supercritical water, which does not exhibit phase separation and remains a single fluid phase. They suggest that the density remains fixed due to the constant volume of the container.
  • This second participant posits that as the temperature is increased beyond the critical point, the water will continue to increase in temperature until molecular decomposition occurs.
  • A later reply expresses appreciation for the previous explanation without introducing new claims.
  • One participant shares a link to a diagram related to water phases, potentially to support their points or provide additional context.

Areas of Agreement / Disagreement

Participants do not reach a consensus on whether water will become steam or remain in a supercritical state when heated above the critical temperature. Multiple competing views remain regarding the behavior of water in this scenario.

Contextual Notes

The discussion does not address specific assumptions about the behavior of water under extreme conditions, nor does it resolve the implications of constant volume on temperature and pressure relationships.

Kasper_NYC
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Hi,

It is supposed a metal container hermetically closed and completely filled with water; the container is supposed to have unlimited strength, so doesn’t deform under internal or external pressure.

What will be happen if we heat the water over its critical temperature (374 C degrees – 705.2 F degrees)? Will it become steam? If yes, how? Because the container is fully filled with water and this is denser than steam (that is a gas).

If doesn’t become steam (gas), will continue the water increasing its temperature over the critical temperature as we increase the temperature we apply?

Thanks a lot.

PS – I apologize for my English, I am learning it.
 
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Well, according to my understanding, above the critical temperature, that is supercritical water and there will be no phase separation. Therefore, there will be only one 'fluid' phase in the region above the critical temperature. it's neither liquid nor gas, but it's still water!Since your container is fixed at constant volume, the density is also fixed. So the water (in fluid phase) will continue increasing its temperature as you increase the temperature outside, until the water molecules decompose.

That is my opinion. If anyone find errors in my words, please correct it. Thanks.
 
Thanks Isloneil for your interesting answer.
 

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