Hard biological materials are uncommon, with egg shells being a notable example. Composed primarily of calcium carbonate (approximately 94%), egg shells also contain magnesium carbonate, calcium phosphate, and organic matter, mainly proteins. The shell features a porous structure that allows for the passage of air, moisture, and bacteria, making up about 11% of the egg's weight. It consists of three layers: the mammillary layer, the middle layer of calcite crystals, and a thin protein cuticle that protects the shell upon laying. The unique arrangement of these crystals provides rigidity while also making the shell susceptible to cracking under certain impacts. This information is corroborated by the USDA's Egg Grading Manual.