What you have written,
[tex]F_{x} = ma = F_{f} - mg \sin (23º) ,[/tex]
indicates that you are placing the x-axis parallel to the slope of the inclined plane already. That puts the "normal direction", which is perpendicular to the inclined plane, parallel to the y-axis, which is why you can write
[tex]F_{n} = mg \cos (23º) .[/tex]
So the friction force is [itex]F_{f} = \mu \cdot F_{n} = \mu \cdot mg \cos (23º) .[/itex] The order in which you wrote the forces for Fx indicates that you have already chosen "uphill" along the incline to be positive. But the block is going to slide "downhill", so ax will be negative. (ay is zero, since the block will not accelerate perpendicularly to the inclined plane; in fact, this was used to come up with Fn - mg cos (23º) = 0 , the second term being the component of the block's weight in the normal direction.
So, yes, your equation should read
[tex]ma_{x} = F_{f} - mg \sin (23º) ,[/tex]
with ax < 0 .
You have to be careful, once you have chosen the directions for the coordinate axes, to be consistent with them in giving the signs to forces, accelerations, velocities, etc. Placing the wrong sign on a term will change the meaning of the force equation and lead to an incorrect solution. (The exception is if all the signs in the entire equation are reversed: this corresponds to pointing that coordinate axis in the opposite direction and will change the sign of the solution, but not the meaning. That is, if positive-x points "downhill" and the acceleration ax is positive, then the object is accelerating downhill; if positive-x points "uphill", then ax will come out negative, but that still representing downhill acceleration.)