What is the correct sign convention for the change in internal energy?

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SUMMARY

The correct sign convention for the change in internal energy (ΔU) can be expressed using two formulas: ΔU = Q - W and ΔU = Q + W. The choice between these formulas depends on the sign convention used for work (W). In ΔU = Q - W, work done by the system on the surroundings is positive, while in ΔU = Q + W, work done on the system by the surroundings is positive. Understanding these conventions is crucial for accurately calculating changes in internal energy in thermodynamic processes.

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  • Understanding of thermodynamic concepts such as internal energy and heat transfer.
  • Familiarity with the first law of thermodynamics.
  • Knowledge of sign conventions in physics and engineering.
  • Basic algebra for manipulating equations.
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  • Study the first law of thermodynamics in detail.
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In my book it says that the change in internal energy = Q -W
Yet, my teacher says that its Q + W
He says that it's reversible due to the signs... but i don't know what that means... can somebody give me an example?
 
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I also know it as Q-W = Delta U.

I can only guess he means it could be Q + W if the figure you have for work is negative, Ie, work done to the system?

Q - -W = Delta U? As a minus and a minus is a plus?

or say

10 - -5 = 15

Hope this helps.
 
The entire difference is in sign conventions; the sign merely depends on your method of thinking on how the system does work on its surroundings.

In the formula delta u=Q-W, W is positive when the system does work on its surroundings and negative when the surroundings do work on the system. For instance, if a balloon is heated, we gain heat (+Q), and the balloon expands, doing work on the surrounding atmosphere (+W). If we would plug this into the equation, we find that the change in internal energy equals the gain of energy from heat minus the energy lost when the system does work.

In the other equation, delta u=Q+W. In this equation, it is assumed that when the surroundings do work on the system, the system gains energy and W is positive. When the system does work on the surroundings, the system loses energy and W is negative. In our expanding balloon example, then, we have energy gained from heat (+Q) minus energy lost through work done by the system (-W).

Either equation works as long as you remember the sign convention. Personally, I prefer the Q+W formula because I find it easier to remember that +W means gaining energy and -W means losing energy, but that's just me. Hope that helps clear things up.
 

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