Entanglement as a quantum state of 2 or more particles took a while to catch on. By the time of Bohm's classic Quantum Theory (1951), electron spin entanglement had been studied a bit and written about. Bohm himself adapted the EPR paradox to electron spin (EPR-B).
There were some early experiments by Bleuler and Bradt (1948) and Wu and Shaknov (1950). Yet it remained something of a curiosity until Bell's Theorem came along (1964). After that, the pace of new work in the area took a big leap. The idea of ruling out local hidden variable theories was a powerful motivator, and research has accelerated since. There are now well over 1000 papers a year published on the subject.