When is the Ionic Product of Water Constant?

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Discussion Overview

The discussion revolves around the conditions under which the ionic product of water, Kw, remains constant at a given temperature in aqueous systems. Participants explore various scenarios, including the influence of acidity and alkalinity on Kw.

Discussion Character

  • Homework-related

Main Points Raised

  • One participant questions whether the problem is asking if Kw is constant across all temperatures or if it never changes, indicating confusion about the question's intent.
  • Another participant asserts that there is no correct answer among the provided options, claiming that Kw is constant at all times.
  • A subsequent reply suggests that the question may be poorly formulated, reflecting a lack of clarity in the original prompt.
  • Another participant agrees with the opinion that the question is problematic.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the clarity of the question, with some agreeing that it is poorly constructed while others focus on the assertion that Kw is always constant.

TT0
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Homework Statement



Under which set of conditions is the ionic product of water, Kw, constant at a given temperature in aqueous systems?

  1. in dilute acidic but not dilute alkaline solutions.
  2. in dilute alkaline but not dilute acidic solutions.
  3. in both dilute acidic and alkaline solutions.
  4. only at the equivalence point of a strong acid-strong alkali titration.
  5. only in pure water.

Homework Equations

The Attempt at a Solution



I don't understand what this question is asking. Is it asking in which scenario is the Kw constant for all temperatures or does it never change? Both of these I don't understand, could someone explain this to me?

Cheers!
 
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Technically there is no correct answer between those given. Kw is constant always.
 
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I see, so its just a bad question then?

Thanks
 
That's my opinion.
 
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