This screen capture didn't work very well, but here is the approach.
It is about 35% down in the right column at:
https://www.sciencedirect.com/topics/earth-and-planetary-sciences/dew-point
It is an excerpt from the book :
Dario Camuffo, in
Microclimate for Cultural Heritage (Third Edition), 2019
The
DP can be easily computed from
RH and air temperature, as in the next formulae. Indeed, considering that the
DP is reached with an isobaric process, the
vapour pressure at the original dry bulb temperature equals the saturation pressure at
DP, i.e.
e(
T) =
esat(
DP). By substituting this finding in formula (3.38), with the help of the Magnus & Tetens formula, one obtains:
(3.48)u=etesatt=eDPesatt=esat0×10aDP/b+DPesat0×10atb+t=10aDP/b+DP−at/b+t
hence
(3.49)logu=aDPb+DP−atb+t
and
(3.50)DP=b+DPalogu+b+DPaatb+t≈b+talogu+t
where the last approximate finding has been obtained substituting
t to
DP in the right-hand side of the first identity. Of course, the first term is negative as
u < 1 and log
u < 0.
Another formula can be derived considering what happens above an evaporating surface. The air temperature lowers, while the increase of
MR raises the
DP. The air temperature
t continues to decrease until the temperature of the evaporating surface, called
wet bulb temperature,
tw, is reached (see Section 3.9). When the evaporated vapour reaches saturation,
t =
tw. Starting from the Clapeyron equation and the definition of
w and always considering the difference
DP −
tw, after some steps and approximations, the following formula is obtained:
(3.51)DP≈bblogu+tlogu+atab−blogu−tlogu
where
a and
b are the Magnus & Tetens coefficients for vapour in equilibrium with the liquid phase. Eq. (3.50) is a better approximation. The formulae can be used once the
RH is known, and obviously
(3.52)logu=logRH100=logRH−2
DP ≤
T and
DP =
T only when
RH = 100%. The
DP is determined once the air temperature
T and the
RH are both known, or also when only the
MR (or
SH) is known. In particular, maxima of
MR correspond to minima of
DP, and vice versa, so that the
DP can be used for diagnostic purposes instead of the
MR and may be useful to express the moisture content in °C.
The
dew point spread (also called
spread), i.e. the difference Δ
DP =
T −
DP basically depends on both the actual air temperature
T and the
MR. Following the approximation (Eq. 3.50 ), it can be expressed as a function of air temperature and
RH
(3.53)ΔDP≈−b+talogu
It physically shows how much the air temperature is close to, or far from, the
DP. The zones having smaller Δ
DP are more prone to form condensation, to allow microbiological life and more intense weathering. Useful maps of this variable can be easily drawn for diagnostic purposes. However, although the
RH is a very different but related variable, in general the areas with
RH maximum are the same as those in which the Δ
DP is minimum. If one is not interested to know how much the ambient is above the dew point, i.e. how much wall temperature (not air temperature!) should be raised to avoid condensation, maps of
RH are sufficient to give a qualitative idea of most critical areas.
Dew has the typical form of droplets and especially forms on leaves during the nocturnal cooling due to the infrared (
IR) emission. The formation of dew on leaves is favoured by the local excess of moisture due to stomatal
transpiration. The surface tension of water tends to displace the larger droplets to the edges of the leaves and in particular to the points of leaves, especially the lance-shaped ones. The upward
IR loss during clear nights is a very effective cooling mechanism. The surfaces on which dew forms are free from any upper shield and in practice are the same that are reached by rainfall. This is the reason why people often believe that dew falls similarly to drizzle. Dew is favoured over vegetated areas, but it occurs on monuments as well, when their surface temperature falls below the
DP. When the temperature of a surface falls below the
DP, in the viscous layer surrounding the surface
RH >100% and condensation occurs.
Hope this helps!
Cheers,
Tom