Why did the salt solution evaporate and leave deposits on the beaker?

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SUMMARY

The discussion centers on the evaporation of a saturated salt solution and the unexpected formation of salt deposits on the beaker. When the solution evaporated overnight, salt crystals formed not only at the bottom but also on the sides of the beaker, exceeding the initial solution height. This phenomenon occurs because evaporation begins at the surface, leading to saturation and crystal formation where the solution contacts the solid beaker, allowing for capillary action to draw more solution up and deposit salt as it evaporates.

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  • Understanding of saturated solutions and solubility principles
  • Basic knowledge of evaporation and condensation processes
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This discussion is beneficial for chemistry students, laboratory technicians, and anyone interested in the physical chemistry of solutions and crystallization processes.

nellocin
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I was messing around with a saturated solution of table salt, when I forgot about it and left it in a fume hood over night. When I came in the next morning the solution had evaporated away, but what surprised me was that there were salt deposits left on the beaker above the initial height of the solution. In fact this is where most of the salt ended up, including some creeping over the top of the beaker. How do I understand this observation?

My expectation was that the water would evaporate molecule by molecule, leaving the salt in the bottom of the beaker. However if the solution evaporated drop by drop, then some drops might hit the side of the beaker on their way out where it could condense leaving salt behind - but this doesn't make sense with the way I understand evaporation.

Any ideas?
 
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Nothing unusual. Solution becomes saturated first on the surface. First crystals form out of the saturated solution in the place where it is in contact with a solid. Then these crystals wick the solution up.
 

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