Why do some Lewis structures have exceptions?

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SUMMARY

The discussion focuses on the Lewis structure of the ICl4- ion, highlighting the challenges of satisfying the octet rule due to the presence of an odd number of electrons. The central iodine atom has 12 electrons, resulting from the single bonds to four chlorine atoms and two lone pairs. The participant expresses confusion regarding the determination of central angles and the existence of exceptions in Lewis structures, seeking better resources for understanding these concepts.

PREREQUISITES
  • Understanding of Lewis structures and the octet rule
  • Familiarity with valence electrons and their calculation
  • Knowledge of molecular geometry and VSEPR theory
  • Basic concepts of ionic charge and its impact on electron distribution
NEXT STEPS
  • Research "VSEPR theory for molecular geometry" to understand bond angles and shapes
  • Study "Lewis structures with expanded octets" for molecules like ICl4-
  • Explore resources on "odd-electron species in chemistry" for handling unpaired electrons
  • Review "common exceptions to the octet rule" for a comprehensive understanding of Lewis structures
USEFUL FOR

Chemistry students, educators, and anyone studying molecular structures and bonding, particularly those interested in advanced Lewis structures and exceptions to standard rules.

QuarkCharmer
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Homework Statement



ICl_4^-

Homework Equations


n/a


The Attempt at a Solution



I has 7 valence, Cl has 7*4. Ideally, they would be 8 and 8*4, and so.
(40-35+1)/2 = 2 bonds. //the +1 is from the negative charge of the ion

There are simply not enough bonds to go around, so when I draw it out I just give a single bond to everything that needs it. Then I make sure that they all satisfy the octet rule and give the leftover electrons to the central atom (I)? So I end up with 4 Cl's with 6 electron dots single bonded to the I, which has an additional 2 lone pair. So I has 12 electrons?

I can understand this one as an example, but what happens when I come up with an odd number of electrons? Is there a decent guide to this somewhere? The only ones that I found are horrible. Also, I am confused as to how exactly you know to make a molecule have more than one central angle?
 
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It seems to me like you're sort of working backwards, and it's confusing you. Here's a guide: http://http-server.carleton.ca/~rburk/chem1000/on_line_tuts/vsepr/ICl4_.htm
 
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