Drawing resonance structure for SO42

In summary, there are six resonance structures for SO42-. However, the structure with single bonds is not considered as one of the possible resonance structures due to its unfavorable spread of formal charges over all four atoms. Although it theoretically exists, its high degree of charge separation makes it significantly less stable compared to the other structures and therefore contributes very little to the resonance hybrid.
  • #1
Sunwoo Bae
60
4
Homework Statement
Draw the important resonance forms for SO42-
Relevant Equations
none
I was told that there are six resonance structures for SO42-, as shown below.

1612005103934.png


I am wondering why this structure with single bonds is not one of the possible resonance.
I understand that it is unfavorable as the formal charges are spread out over all four atoms, but shouldn't is still be a part of the resonance, given that the total formal charge of the molecule adds up to 2- in total?

1612005230638.png


Thank you
 
Last edited by a moderator:
Physics news on Phys.org
  • #2
Theoretically that is a possible resonance structure, but that degree of charge separation makes it much less stable than the other structures, so it contributes very little to the resonance hybrid.
 

1. What is the chemical formula for SO42?

The chemical formula for SO42 is sulfate. It is composed of one sulfur atom and four oxygen atoms.

2. What is resonance in chemistry?

Resonance in chemistry refers to the phenomenon where the electrons in a molecule are delocalized, meaning they are not confined to a single bond or atom. This results in the molecule having multiple possible structures, known as resonance structures.

3. How do you draw resonance structures for SO42?

To draw resonance structures for SO42, start by identifying the central atom, which is sulfur. Then, draw the different possible arrangements of electrons around the sulfur atom, while keeping the overall charge and number of atoms the same. These structures can be represented using dashed or dotted lines to indicate the delocalized electrons.

4. Why is it important to draw resonance structures for SO42?

Drawing resonance structures for SO42 helps to accurately represent the molecule's structure and electron distribution. This is important in understanding the molecule's properties and reactivity. Additionally, it allows us to visualize the different possible forms of a molecule and how they contribute to its overall stability.

5. Can resonance structures be used to predict the reactivity of SO42?

Yes, resonance structures can be used to predict the reactivity of SO42. The more stable resonance structures contribute more to the overall structure, and therefore, the molecule is more likely to react in a way that is consistent with these structures. Additionally, the presence of multiple resonance structures indicates that the molecule is more stable, making it less reactive.

Similar threads

  • Biology and Chemistry Homework Help
Replies
9
Views
1K
  • Biology and Chemistry Homework Help
Replies
2
Views
2K
  • Biology and Chemistry Homework Help
Replies
1
Views
626
  • Biology and Chemistry Homework Help
Replies
3
Views
4K
  • Biology and Chemistry Homework Help
Replies
1
Views
3K
  • Biology and Chemistry Homework Help
Replies
1
Views
2K
  • Biology and Chemistry Homework Help
Replies
11
Views
8K
  • Biology and Chemistry Homework Help
Replies
1
Views
1K
  • Biology and Chemistry Homework Help
Replies
4
Views
2K
  • Biology and Chemistry Homework Help
Replies
1
Views
7K
Back
Top