A freely falling body undergoes no proper acceleration; proper acceleration is what you measure with an accelerometer. Acceleration due to gravity is, in a very loose sense, analogous to inertial forces from Newtonian mechanics such as the centrifugal and Coriolis forces. More precisely, imagine we have a non-rotating spherically symmetric star generating the gravitational field of interest. An observer, let's call him ##O##, hovers outside of the star with a rocket. Another observer ##O'## is freely falling and at an event ##p## passes right by ##O##. Now by definition ##O'## has no proper acceleration because he is freely falling. On the other hand ##O## does have a proper acceleration because he is using the thrusters of his rocket to counter the gravitational field so that he can just hover in place; this proper acceleration is the magnitude of an acceleration vector ##\vec{a}##. Say now we go to the rest frame of ##O##. When ##O'## falls past him at ##p##, ##O## will attribute to ##O'## the acceleration ##\vec{g} = -\vec{a}## because we're in the rest frame of ##O## and at ##p## we have ##O'## freely falling down past ##O##. This ##\vec{g} = -\vec{a}## is the gravitational acceleration.
To make it a bit more concrete, consider the uniform gravitational field within the Earth. You're standard on the ground so the ground is pushing you up with a proper acceleration ##a = 9.81 m/s^2##. A person that's freely falling towards the ground after being dropped from the sky (we ignore air resistance) has no proper acceleration by definition. However you, in your rest frame, say that the person is accelerating down towards the ground at a rate ##g = -9.81m/s^2##. This is what you normally call the gravitational acceleration but as you can see it's in a loose sense like an inertial force arising from the fact that you have an acceleration ##\vec{a}## of which the proper acceleration exerted by the ground on your feet is the magnitude and in your rest frame this manifests itself as an acceleration ##\vec{g} = -\vec{a}## of a freely falling object.
EDIT: I would recommend that you, for the time being, ignore the fact that freely falling observers locally have truly straight world-lines (we say that they are locally inertial observers). This will be a hard thing to understand until you have more math under your belt.