Why does temperature rise with pressure?

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Discussion Overview

The discussion centers around the relationship between temperature and pressure in gases and liquids, particularly exploring the molecular-level mechanisms that lead to temperature changes during compression. Participants examine concepts related to the Ideal Gas Law, kinetic energy, and the effects of work done during compression.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant expresses confusion about how temperature can increase with pressure, questioning the role of molecular collisions and elastic interactions.
  • Another participant asserts that the work done during compression is the energy that increases temperature.
  • Some participants suggest that increased collisions due to higher pressure lead to increased molecular movement, which is associated with higher temperature.
  • A participant explains that the force exerted by a piston compressing gas increases the speed of gas molecules, thereby increasing their kinetic energy.
  • There is a discussion about whether temperature is affected by pressure or if it is solely a function of compression, with differing opinions on the relationship between these variables.
  • Some participants argue that compressing a gas increases the density of energy within a given volume, which could lead to a rise in temperature.
  • Concerns are raised about the implications of these ideas on established gas laws, such as the Ideal Gas Law and Charles's Law.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the relationship between temperature and pressure, with multiple competing views remaining. Some argue that temperature is influenced by compression, while others maintain that pressure does not affect temperature without external forces.

Contextual Notes

Participants highlight potential limitations in understanding, such as the dependence on definitions of energy, heat, and kinetic energy, as well as the implications for established gas laws that remain unresolved.

Who May Find This Useful

This discussion may be of interest to individuals exploring thermodynamics, gas laws, and the molecular behavior of gases under varying conditions, particularly those seeking a deeper conceptual understanding of temperature and pressure relationships.

  • #31
If you apply force to a liquid, wishing to compress it, but it is incompressible, then no work is done on the liquid. No energy is provided to the liquid.

But you have certainly lost some energy, it has gone into your metabolic processes and has been released into the atmosphere. Basically, it has been wasted.


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  • #32
Jumping into this a couple years late :)

I find it hard to accept that the increase in temperature is only because of a moving surface. The argument seems to be that just like a tennis ball, the molecules bounce off the moving surface (tennis raquet) and increase their speed.

The problem I have is that the speed of the molecules is so much faster than the speed of the surface. It seems to me that the increase in speed that the moving surface imparts would have a very small increase in the temperature. It almost seems like it would be a negligible increase ... 0.00something percent. But as we know the temperature rises quite appreciably.

Consider a propane container used for your standard BBQ grill. As you use the propane with your grill turned on, the container gets very cold. What is happening here? The number of molecules in the container are decreasing. But the walls of the container are not moving? How then are the molecules moving slower if they are not striking a backwards moving surface (as was previously argued). There has to be some component to the change in temperature added by the fact that distances between molecules changes with changing pressure.
 
  • #33
DreadPR said:
I find it hard to accept that the increase in temperature is only because of a moving surface. The argument seems to be that just like a tennis ball, the molecules bounce off the moving surface (tennis raquet) and increase their speed.

The problem I have is that the speed of the molecules is so much faster than the speed of the surface. It seems to me that the increase in speed that the moving surface imparts would have a very small increase in the temperature. It almost seems like it would be a negligible increase ... 0.00something percent. But as we know the temperature rises quite appreciably.

Hi DreadPR, welcome to PF. Yep, this thread is five years old, and some of the original players are no longer active. The moderators may move it to a new thread if they desire.

You need to consider that the same molecule gets many, many momentum-increasing "kicks" as the surface moves inward. (Alternatively, you could calculate how fast the surface would have to move to give an arbitrary molecule just one kick. You'll find it's comparable to the molecular speed.)

DreadPR said:
Consider a propane container used for your standard BBQ grill. As you use the propane with your grill turned on, the container gets very cold. What is happening here? The number of molecules in the container are decreasing. But the walls of the container are not moving? How then are the molecules moving slower if they are not striking a backwards moving surface (as was previously argued). There has to be some component to the change in temperature added by the fact that distances between molecules changes with changing pressure.

The gas inside the container is doing work on the gas that leaves the container, and thus its temperature decreases, also decreasing the container temperature.
 
  • #34
Mapes said:
You need to consider that the same molecule gets many, many momentum-increasing "kicks" as the surface moves inward. (Alternatively, you could calculate how fast the surface would have to move to give an arbitrary molecule just one kick. You'll find it's comparable to the molecular speed.)

Thanks for the welcome and the quick response :)

Yes I didn't consider that there would be many many kicks.
 

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