Why Does the Crystal Model Use Squared Combinations for State Count?

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The discussion centers on calculating the number of states in a crystal with N lattice points and interstitial positions. It begins with the formula for choosing n atoms from N, given as C_{N}^n = N!/(n!(N-n)!), which represents the configurations for filling interstitial sites. However, the example states the number of states as Ω = (C_{N}^n)^2, raising questions about its validity. The clarification provided explains that the squared term accounts for the dual selection process: choosing atoms to fill interstitial sites and the gaps they leave behind. This reasoning resolves the initial confusion regarding the example's formulation.
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In textbook of statistical mechanics, there is an example considering an idealization of a crystal which has N lattice points and the same number of interstitial positions (places between the lattice points where atoms can reside). Let E be the energy necessary to remove an atom from a lattice site to an interstitial position and let n be the number of
atoms occupying interstitial sites in equilibrium. Now try to find the number of state

It is quite easy to think about this: choose n atoms from N atoms to fill n interstitial positions, number of possible configuration is given by combination


C_{N}^n = \frac{N!}{n!(N-n)!}

I think the number of state should be

\Omega = C_{N}^n = \frac{N!}{n!(N-n)!}

but the example just put

\Omega = \left(C_{N}^n\right)^2 = \left(\frac{N!}{n!(N-n)!}\right)^2

without saying why. Do you think it is a mistake?
 
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KFC said:
… an idealization of a crystal which has N lattice points and the same number of interstitial positions (places between the lattice points where atoms can reside).
Let E be the energy necessary to remove an atom from a lattice site to an interstitial position and let n be the number of
atoms occupying interstitial sites in equilibrium.
Now try to find the number of state

the example just put

\Omega = \left(C_{N}^n\right)^2 = \left(\frac{N!}{n!(N-n)!}\right)^2

without saying why. Do you think it is a mistake?

Hi KFC! :smile:

the atoms have to come from somewhere,

and they've left gaps behind them …

so there are NCn ways of choosing where they're from, and NCn ways of choosing where they're going. :wink:
 
tiny-tim said:
Hi KFC! :smile:

the atoms have to come from somewhere,

and they've left gaps behind them …

so there are NCn ways of choosing where they're from, and NCn ways of choosing where they're going. :wink:

Got it. Thanks tiny-tim, you help me a lot.
 
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