Why Does the Crystal Model Use Squared Combinations for State Count?

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SUMMARY

The discussion centers on the calculation of the number of states in a crystal model, specifically addressing why the state count is represented as squared combinations. The formula for the number of configurations is given by CNn = N! / (n!(N-n)!), but the example states that the total number of states is Ω = (CNn)2. This is justified by recognizing that there are NCn ways to choose atoms from lattice sites and NCn ways to choose interstitial positions, leading to the squared term. The clarification provided by forum member tiny-tim confirms this reasoning.

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In textbook of statistical mechanics, there is an example considering an idealization of a crystal which has N lattice points and the same number of interstitial positions (places between the lattice points where atoms can reside). Let E be the energy necessary to remove an atom from a lattice site to an interstitial position and let n be the number of
atoms occupying interstitial sites in equilibrium. Now try to find the number of state

It is quite easy to think about this: choose n atoms from N atoms to fill n interstitial positions, number of possible configuration is given by combination


[tex]C_{N}^n = \frac{N!}{n!(N-n)!}[/tex]

I think the number of state should be

[tex]\Omega = C_{N}^n = \frac{N!}{n!(N-n)!}[/tex]

but the example just put

[tex]\Omega = \left(C_{N}^n\right)^2 = \left(\frac{N!}{n!(N-n)!}\right)^2[/tex]

without saying why. Do you think it is a mistake?
 
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KFC said:
… an idealization of a crystal which has N lattice points and the same number of interstitial positions (places between the lattice points where atoms can reside).
Let E be the energy necessary to remove an atom from a lattice site to an interstitial position and let n be the number of
atoms occupying interstitial sites in equilibrium.
Now try to find the number of state

the example just put

[tex]\Omega = \left(C_{N}^n\right)^2 = \left(\frac{N!}{n!(N-n)!}\right)^2[/tex]

without saying why. Do you think it is a mistake?

Hi KFC! :smile:

the atoms have to come from somewhere,

and they've left gaps behind them …

so there are NCn ways of choosing where they're from, and NCn ways of choosing where they're going. :wink:
 
tiny-tim said:
Hi KFC! :smile:

the atoms have to come from somewhere,

and they've left gaps behind them …

so there are NCn ways of choosing where they're from, and NCn ways of choosing where they're going. :wink:

Got it. Thanks tiny-tim, you help me a lot.
 

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