Biker said:
In my book, It says energy is proportional to the square of amplitude. It doesn't depend on frequency.
Then the book is not about quantum mechanics or the introduction to it. As far as Electromagnetic waves are concerned, it is indeed the case that the total
SUM of all photons detected is the energy of the wave, which would be simpler to just detect the electric or magnetic wave and deal with it from there, no need to sum 'gazillions' of particles individually if to use a technical term, you already do that by measuring the fields.
As for why in a reflection the frequency does not change, we must also remember that their speed doesn't change as it depends on universal constants, thus to satisfy c=λf, it must mean that the wavelength also does not change. From here we can work our way forward using Einstein's equation for Energy and momentum relationship in Spacial relativity. We also need to use the finding from Black Body Radiation that the energy is coming in packets, essentially there is a minimum amount of electric field fluctuation which is associated with a photon, as you must introduce in the equations that light is both a wave and a particle.
Math warning:
Using the following equations:
E
2=(mc
2)
2+(pc)
2 , m-mass, E-energy, p-momentum, c-speed of light
E=hf, for photons (and remember, photons have momentum), h-planck's constant, f-frequency of the photon
c=λf, λ-wavelength of the photon
And conservation of momentum you will be able to arrive at the situation that should a free electron be hit by a photon, not only does the electron get deflected, a photon of a different wavelength must be emitted, and thus satisfying elastic collisions, there really is no other way to get rid of the excess energy other than heat (which is emitted by photons).
You will also get this relationship with some hard work and probably another equation I may have left out:
λ'-λ=h[1-cos(θ)]/(m
ec)
where λ' is the new wavelength, m
e is the mass of the electron, and θ is the angle at which the photon is deflected.
Without a re-emission you'd get only one term to change without any other term to change thus meaning the speed of light, Planck constant or the mass of the electron change at classical limits, and using Einstein's equation we arrive at mc=0.
So electrons should move and photons change wavelength depending on angle of re-emission, right?
Except in material we don't find free electrons unless it is a conductor(which is an interesting topic by itself but not necessary for us here). Thing is, the electrons according to the Bohr Model are bound, and can change their kinetic energy (and the picture now gets ridiculous as now not every photon can be received), so the electron can now 'eat' the photon entirely and get more energy, now no photon must be re-emitted in order to conserve both momentum and energy. Except electrons will lose energy spontaneously and emit new photons which sum up to the energy of the original one, many times the same frequency as well, and also most of them will adhere to the law of reflection on the macro scale, because nature works like that, the minimum.
TL;DR
Assuming the reflector remains stationary, which for electrons bound in an atom is true, and walls of material for mechanical waves (slight fib, but won't go deeper), the reflection will adhere to the angle of reflection is the same as the angle of attack.
NOTE: There might be a problem with my second paragraph as it seems like I am missing 1 or 2 equations to get to the final equation of free electron hit by a photon.