f you put a dielectric between the plates, the molecules in faces of the the dielectric are much nearer to each plate and the molecules inside the dielectric will polarise easily. So, again, the actual charge imbalance on the plates will be greater for a given PD. Another way I look upon a dielectric is that it's a bit like putting a conductor in between that's just a tiny bit narrower than the original gap. That is producing a capacitor with a much smaller gap and, hence, a greater Capacitance. The only problem is that such a narrow gap between metal plates could flash across with only a tiny PD. A dielectric will only allow Polarisation and not a flow of charge so no 'short circuit'.