Why is d<xp>/dt = (i/hbar)<[H,xp]> = 0 for a stationary state?

AI Thread Summary
The discussion centers on a problem from Liboff's "Introductory Quantum Mechanics - 3rd Ed." regarding the relationship between kinetic energy and the potential in a stationary state. The key point of confusion is why the time derivative of the expectation value of the product of position and momentum, d<xp>/dt, equals zero in a stationary state. The explanation provided references the Heisenberg equation of motion for operators, which indicates that for operators like position (x) and momentum (p) that do not have explicit time dependence, the partial derivative with respect to time is zero. Consequently, in a stationary state, the expectation values do not change over time, leading to the conclusion that d<xp>/dt is indeed zero. This clarification resolves the initial confusion about the nature of expectation values in stationary states.
pmb
There's a problem in Liboff's text "Introductory Quantum Mechanics - 3rd Ed."

On page 176 problem 6.12 states

"A particle moving in one dimension interacts with a potential V(x). In a stationary state of this system show that

(1/2) <x dV/dx > = <T>

where T = p^2/2m is the kinetic energy of the particle."

Liboff gives the answer but starts off with

"In a stationary state,

d<xp>/dt = (i/hbar)<[H,xp]> = 0
..."

Why? I.e. why is d<xp>/dt = (i/hbar)<[H,xp]> = 0 for a stationary state?

Pete
 
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Originally posted by pmb
Why? I.e. why is d<xp>/dt = (i/hbar)<[H,xp]> = 0 for a stationary state?

Look up the Heisenberg equation of motion for operators. The equation is:

dO/dt=(i/hbar)[H,O]+&part;O/&part;t

for any operator O. Evidently, x and p have no explicit time dependence in your problem so the partial with respect to t is zero. The derivation should be in your book, but the basic reason is that the Hamiltonian is the generator of time translations, and so you would expect it to be closely associated with the time evolution of operators.
 


Originally posted by Tom
Look up the Heisenberg equation of motion for operators. The equation is:

dO/dt=(i/hbar)[H,O]+&part;O/&part;t

for any operator O. Evidently, x and p have no explicit time dependence in your problem so the partial with respect to t is zero. The derivation should be in your book, but the basic reason is that the Hamiltonian is the generator of time translations, and so you would expect it to be closely associated with the time evolution of operators.

{Note: Liboff is is a quick review for me for the summer so I've bneen through this before - but 10 years ago. We used Cohen-Tannoudji in grad school - both semesters - so I'm brushing up to jump into that}

What you've said is in a way related to this section in a certain sense - this was a section on the relation

d<A>/dt = <i/hbar [H,A] +&part;A/&part;t>

In this case A = xp. Th partial drops out and we're left with


d<ap>/dt = i/hbar <[H,xp]>

But Liboff sets that to zero - why?

Pete
 


Originally posted by pmb
d<ap>/dt = i/hbar <[H,xp]>

But Liboff sets that to zero - why?

OK, now I understand your question. He sets it to zero because you are looking at an expecation value, which for stationary states does not evolve in time (by definition of "stationary state"). Take away the < > brackets, and you do not necessarily get zero.
 


Originally posted by Tom
OK, now I understand your question. He sets it to zero because you are looking at an expecation value, which for stationary states does not evolve in time (by definition of "stationary state"). Take away the < > brackets, and you do not necessarily get zero.
'

Ahhh! The expectation for any operator for a stationary state is a constant in time!

Okay - Thanks. I get it now. Duh! :-) I can't see why I missed that now. Thanks Tom

Pete
 
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