Why is E = hf applicable to electrons with quantized energy?

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E = hf can be applied to electrons because it relates energy changes to frequency, particularly during transitions between energy levels. While traditionally associated with photons, this equation also describes the quantum-mechanical frequency of particles like electrons, which possess wave-like properties. The frequency can be calculated using the total energy of the electron, including both rest mass and kinetic energy. The relationship between energy and frequency for particles is consistent with the principles of quantum mechanics, as demonstrated through the Schrödinger equation. Understanding these concepts is essential for grasping the broader implications of wave-particle duality in quantum physics.
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I came across a problem my teacher assigned. We are asked to calculate frequency of electron having certain energy. My teacher used E = hf to solve the problem. I thought that could only be applied to photon. Is it because electron has wave-like nature and has quantized energy?
 
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Okay . You need to clear your fundamentals from your teacher.
E=hf. does not give the energy of electron. It gives the energy required / released when electrons change their energy levels. And this energy may be radiated in the form of photons or by heat or any other form.

I recommend you to go through Bohr's postulates regarding Atomic model.
 
The question is given like this:
electron has 511keV and kinetic energy of 100 MeV and determines its frequency.
the answer is 2.43*10^22 Hz, which can be determined through f = E/h.

I just wonder how can my teacher use the equation like that for such straightforward question.
 
budafeet57 said:
The question is given like this:
electron has 511keV and kinetic energy of 100 MeV and determines its frequency.
the answer is 2.43*10^22 Hz, which can be determined through f = E/h.

I just wonder how can my teacher use the equation like that for such straightforward question.
It's the frequency corresponding to the electron's De Broglie wavelenght. E = 100.511 MeV, f = E/h.
 
It is a quantum-mechanical frequency, and the connection between energy and frequency is the same for all particles.
 
E=hf is fine for describing the energy associated with a photon but I am not familiar with assigning frequency to energy for a particle. There is a relationship between wavelength (de Broglie) and momentum for particles (P=h/λ) but where does a constant relationship between Energy and Frequency for particles come in? Where would that leave the equation for waves 'c=fλ' for instance?
What am I missing here?
 
This comes from relativistic wave equations - but even in the "classic" case, an electron with 100 MeV kinetic energy has E≈pc=hc/λ=hcf/v≈hf.
 
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We can connect E = hf for an electron to the Schrödinger equation for matter waves by examining the time dependency of a stationary state.

| \Psi (t)> = e^{-iE_{n}t/\hbar}| n>

Where |n> represents a stationary (stable) state at time zero, and En represents the energy of that state. Now, if we substitute into the above equation the following:

E_{n} = hf = \hbar \omega = \hbar 2\pi f

Then, we'd get

| \Psi (t)> = e^{-i2\pi ft}| n >

Notice that the exponential multiplying the stationary state has a frequency of magnitude f. So the phase of a stationary state of a matter wave (from Schrödinger's equation) cycles at a frequency given by the energy of the state and the equation E = hf.
 
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