Why is the air transparent and what makes most gases have low absorption?

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    Air Transparent
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SUMMARY

The transparency of air to visible light is primarily due to the low density of its main components, nitrogen and oxygen, which scatter little light and do not absorb visible wavelengths. The absorption spectrum of gases is discrete, allowing most visible light to pass through without interaction. This phenomenon is crucial for human vision, as our eyes have evolved to detect light in the spectral regions that are least affected by atmospheric gases. Additionally, the interaction of light with materials varies by frequency, explaining why certain materials, like glass, are transparent to visible light but opaque to infrared radiation.

PREREQUISITES
  • Understanding of atomic transitions (electronic, vibronic, rotational)
  • Knowledge of the electromagnetic spectrum, particularly visible light and infrared
  • Familiarity with the concepts of light scattering and absorption
  • Basic principles of optics and human vision
NEXT STEPS
  • Research the electromagnetic spectrum and its interaction with different materials
  • Learn about atomic absorption and emission spectra in gases
  • Explore the principles of light scattering and its applications in atmospheric science
  • Investigate the role of human vision in perceiving light and color
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Students of physics, atmospheric scientists, and anyone interested in the principles of light and vision will benefit from this discussion.

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Why are the atmosphere's main elements ( Nitrogen and Oxygen) transparent to visible light.

And what makes most gases have low absorption?
 
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Gases scatter little light becasue they have low density. The spectral location of absorption lines depends on allowed atomic (electronic, vibronic, rotational) transitions, and for Earth's atmosphere, our eyes have evolved to take advantage of spectral reagions with little scattering.
 
I think Andy has really hit on the explanation here. I don't think it's an oddity that atmospheric gases don't have absorption lines in the visible spectrum but rather that's one of the main reasons why the visible spectrum of our eye is what it is (as opposed to the IR region or the likes)
 
Isn't there also a reason related to the fact that a solid (at least crystalline solid) has energy bands while a gas is made of isolated molecules and therefore has energy lines? Could this mean that in white light a typical solid would absorb/block entire bands of wavelengths, while a gas would only block some monochromatic frequencies and therefore it would let most of the white light go through?

...or am I making this up? :)
 
There are basically 2 reasons. For one, air is rarefied. The molecules are not very close together so that like waves (or particles) are not likely to collide with an air molecule along its trajectory. In other words, it has a very long mean free path.

Also, and probably more important, none of the molecules that make up air absorb the frequencies of light that are visible to the human eye. Therefore, they do not absorb light and re-emit it at a different frequency as colored things do and that makes the air transparent to visible light.
 
If your eye was built for a different wave-length, say at gamma ray level, you would be asking "why is aluminium transparent" instead.

basically, the frequency of a wave decides how it interacts with different materials. The range which we call "visible light" happen to pass through glass unaltered, while the range we call heat-waves does not.

This is one of the reasons why your car gets so damn hot in the summer: Light comes though the windows and bounces from the interior. It looses some energy during that bounce, and becomes a heatwave. Same thing, different frequency. Only, heat does not pass unaltered through the glass, so it is trapped inside and bounces back and forth, heating your car.

k
 
kenewbie said:
<snip>

This is one of the reasons why your car gets so damn hot in the summer: Light comes though the windows and bounces from the interior. It looses some energy during that bounce, and becomes a heatwave. Same thing, different frequency. Only, heat does not pass unaltered through the glass, so it is trapped inside and bounces back and forth, heating your car.

k

This is not true- simply allowing the IR radiation to get into the car and be absorbed by the car interior is sufficient to explain the behavior. One not need presume that visible light be 'down-shifted' to IR radiation, nor that IR radiation be 'captured' within the car interior. Neither occurs.

Finally, a small quibble- heat and IR radiation are not the same things.
 
Andy Resnick said:
This is not true- simply allowing the IR radiation to get into the car and be absorbed by the car interior is sufficient to explain the behavior. One not need presume that visible light be 'down-shifted' to IR radiation, nor that IR radiation be 'captured' within the car interior. Neither occurs.

Finally, a small quibble- heat and IR radiation are not the same things.

kenewbie's response, also works with the visible light, but like Mr. Resnick said, there is no redshift of that light into IR. The materials in the car may absorb some of the visible light converting that energy into heat. But as Mr. Resnick said, heat is not light; thus is gets trapped in your motorized greenhouse.
 
Andy Resnick said:
This is not true- simply allowing the IR radiation to get into the car and be absorbed by the car interior is sufficient to explain the behavior.
I though the idea here was that windows are transparent to visible light but somewhat opaque to IR.
 
  • #10
So if a height intensity laser beam was adjusted to one the frequencies of oxygen visible spectrum, would light scattering be observable ?
 
  • #11
The best answer (in the sense that it provides the full overview) is the one given by Domenicaccio. Gases are transparent because their absorption spectrum is discrete rather than continuous. The reason for the discreteness is the inability to support collective excitations because of the weak interaction strength between molecules that are widely separated.
 
  • #12
None of these answers make sense. If we see though air (i.e., it appears transparent) because it's molecules are less dense than light waves of the visible spectrum, how do we "know" that the light comes from the surfaces of objects. That is, how do we attribute the light to the surface and not the air in front of the surface?
 
  • #13
None of these answers make sense. If we see though air (i.e., it appears transparent) because it's molecules are less dense than light waves of the visible spectrum, how do we "know" that the light comes from the surfaces of objects. That is, how do we attribute the light to the surface and not the air in front of the surface?
 
  • #14
What?
 
  • #15
What?10char[/color]
 
  • #16
DaveC426913 said:
I though the idea here was that windows are transparent to visible light but somewhat opaque to IR.

That's true; but I think the more important factor for your car heating up is that the air gets trapped by the roof and sides. Outside, the air heated at the surface is continually replaced by cooler air from aloft, by circulation.

The question of the thread can be rephrased: why are our eyes particularly sensitive to wavelengths where there is the most light passing easily through the air? The visible portion of the spectrum is both the peak of the solar radiation, and also in a band that does not interact with atmospheric gases.

Cheers -- sylas
 
  • #17
The question is really straight-forward. Light waves reflect off of objects that then stream into the eye by first traveling from the object through open space. How is it that we determine where the object is located? That is, why don't we "see" the stream of light waves as they travel in the open space (so that it appears like a colored volume rather than a distant opaque surface)? Instead we somehow decide that the stream of light originates at the surface of the object and then we eliminate our perception of that stream from the intervening space.
 
  • #18
Schirillo said:
The question is really straight-forward. Light waves reflect off of objects that then stream into the eye by first traveling from the object through open space. How is it that we determine where the object is located? That is, why don't we "see" the stream of light waves as they travel in the open space (so that it appears like a colored volume rather than a distant opaque surface)? Instead we somehow decide that the stream of light originates at the surface of the object and then we eliminate our perception of that stream from the intervening space.

No, that's wrong. The reason we don't see the stuff in between is it has no effect on the light; it really DOES originate at the opaque surface. We don't see the light as coloured because it ISN'T coloured. If something is transparent... like the air... then light is passing through it without any effect. There's no special role for "eliminating perception". A machine measuring that light would also be measuring the surface that emits the light, just like the eye.

Cheers -- sylas
 
  • #19
But the question remains, how does the eye (or a machine) "know" that the light originates at the opaque surface (and not closer to the eye)? Machines don't have depth perception. They only "see" in two-dimensions, without imposing some amount of empty (transparent) space between their receptors and the surface.
 
  • #20
Schirillo said:
But the question remains, how does the eye (or a machine) "know" that the light originates at the opaque surface (and not closer to the eye)? Machines don't have depth perception. They only "see" in two-dimensions, without imposing some amount of empty (transparent) space between their receptors and the surface.

You can have depth perception with machines just fine; it's not magic.

Your question makes no sense. It's not about "knowing". The point is that the light ACTUALLY DOES originate at the surface -- whether you know this or not, and regardless of whether the light is received by a thinking being capable of "knowing" things, or a dumb machine that just makes measurements.

That's why it is incorrect to say that there's some kind of special "perception" process involved in eliminating the effects of stuff in between. There's nothing to eliminate.

There are certainly some odd things that can happen with perception. Here's my favourite; the human perception system sees blue and green spirals; but if you test the image more carefully, you can check that they are really the same color.
colors.gif

(Reference: The blue and the green -- Bad Astronomy Blog).

The point is, the invisibility of air is NOT a perception effect. It is because the air actually is transparent to visible light. This question is one of the physics of light and matter; not about perception and knowledge.

sylas
 
  • #21
The question is not what actually exists (I know the light originates at the surface), it's what is perceived; just like the perception of transparency.

It does have to do with knowledge, since machines cannot perceive depth unless they emit a signal that bounces back off the surface (like bats using echolocation). There is no way to determine depth from just an incoming signal.

The spiral picture you've posted is simple simultaneous contrast, also known as induction. It can be explained by psychophysicists, my question cannot.
 
  • #22
Schirillo said:
The question is not what actually exists (I know the light originates at the surface), it's what is perceived; just like the perception of transparency.

It does have to do with knowledge, since machines cannot perceive depth unless they emit a signal that bounces back off the surface (like bats using echolocation). There is no way to determine depth from just an incoming signal.

This is now just being silly.

Machines use exact same incoming signal we do. We get depth perception from that signal not by magic, but by primarily by having two eyes, for binocular vision. Machines can also have two light detectors, or two cameras, and pick up depth perception in precisely the same way, looking at the incoming signal at two different points. There's quite a lot of work doing just that.

Comically, you've actually demolished your own point when you talk about incoming signals. THAT'S what is important. The incoming signal DOES include depth information, but it does not include information about a transparent medium. That's why it is silly to say this is about "perception", when of course it is about the physics of how light and air interact, and what happens to the incoming signal; no matter WHAT is used to detect or measure it.

Your question cannot be tackled by psychology or brain studies, because this has nothing to do with "perception". That's the whole point. Transparency is not a "perception" effect, but about what can physically occur with an incoming signal, independent of what might be used to measure or perceive it. In other words: the question most definitely IS about what actually exists in the light signal.
 
  • #23
It's not "silly". You can see in depth just fine with just one eye (just cover one and check), but a machine can't.

The incoming signal DOES NOT include depth information (if you exclude binocular receptors)...all it contains are wavelengths of light. These wavelengths are not colored, nor do they contain a "separate depth signal"
 
  • #24
It's not "silly". You can see objects in depth with just one eye (cover one eye and notice that virtually nothing changes), however machines need stereo (or some form of triangulation). The incoming signal DOES NOT include depth information, it only contains wavelengths of light, not an additional signal as to where those wavelengths originated.
 
  • #25
Schirillo said:
It's not "silly". You can see objects in depth with just one eye (cover one eye and notice that virtually nothing changes), however machines need stereo (or some form of triangulation). The incoming signal DOES NOT include depth information, it only contains wavelengths of light, not an additional signal as to where those wavelengths originated.

Pretty much everything you've said above is flatly wrong.

The idea that the incoming signal does not contain depth information is false. How do you think the eye figures it out? It figures it out because light signals have direction, which gives a different view in two eyes. This is depth information. You look at the angle from which a signal comes, in one eye and in the other (triangulation).

As I said before, there is quite a lot of work with robots that do depth perception using binocular vision, just like we do. They don't use magic; they just use the incoming signal.

You also get a much less effective depth vision with one eye, by changes in focus; which is pretty much the same thing but over the space of the retina rather than the space between two eyes. It is, of course, nonsense to say that covering an eye changes virtually nothing. It kills your depth perception, and that makes a huge difference, as anyone who has an eye out of action for any time swiftly discovers. You need stereo vision to get at the depth information available in light coming from some object.

Getting back to the point of the thread. The transparency of air is a physical aspect of light signals passing through air. The transparency of air is a property of light and air, not of the eye and mind.
 
  • #26
sylas said:
Pretty much everything you've said above is flatly wrong.

The idea that the incoming signal does not contain depth information is false. How do you think the eye figures it out? It figures it out because light signals have direction, which gives a different view in two eyes. This is depth information. You look at the angle from which a signal comes, in one eye and in the other (triangulation).

As I said before, there is quite a lot of work with robots that do depth perception using binocular vision, just like we do. They don't use magic; they just use the incoming signal.

You also get a much less effective depth vision with one eye, by changes in focus; which is pretty much the same thing but over the space of the retina rather than the space between two eyes. It is, of course, nonsense to say that covering an eye changes virtually nothing. It kills your depth perception, and that makes a huge difference, as anyone who has an eye out of action for any time swiftly discovers. You need stereo vision to get at the depth information available in light coming from some object.

Getting back to the point of the thread. The transparency of air is a physical aspect of light signals passing through air. The transparency of air is a property of light and air, not of the eye and mind.

He wasn't saying they use "magic", but rather, they build up a virtual model of the world based upon past and present information and use the whole model to judge things like distance rather than information that is based solely on what is currently hitting the eye.
 
  • #27
Schirillo said:
It's not "silly". You can see objects in depth with just one eye (cover one eye and notice that virtually nothing changes)

Have you actually done any work which requires ACTUAL depth perception with one eye? I do from time to time (my left eye is a bit dodgy and from time to time it doesn't work very well) and I can assure you that depth perception with one eye is nowhere near as good as with two eyes.
Yes, it can be done but it is to a large extent based on experience; if you know the size of an object you can judge the distance by looking at its relative size, i.e. the same way we perceive "depth" when watching a movie on TV.
E.g doing anything complicated under a microscope is nearly impossible for me since the "size" information does not work anymore.
Another "trick" which the brain does use automatically is to continuously re-focus the eyes (which gets very tiring after a while) which gives some limited information about depth.

Also, remember that the difference between a 3D movie and an ordinary 2D movie is that the former conveys unique information to each eye; this is what makes it 3D.
If what you are saying were correct there wouldn't be any difference between 2D and 3D.
 
  • #28
Schirillo said:
None of these answers make sense. If we see though air (i.e., it appears transparent) because it's molecules are less dense than light waves of the visible spectrum, how do we "know" that the light comes from the surfaces of objects. That is, how do we attribute the light to the surface and not the air in front of the surface?

If you are asking about how our brain deciphers the signals coming from the lightsensitive neutrons in our eyes... I have know idea (And I properbly got the description wrong too).

As to how we can see objects in the distance and "know" they aren't actually located 2 cms away, well we have stereo vision, and also we can move our heads around a bit to determine if something is close or far away. There is no real "origin" information encoded in the light, if it did come from somewhere in between you and the object, our eyes wouldn't be able to tell so. Consider movies, which slightly trick your brain into thinking something isn't just a flat projection of chaning colors, or even better consider holograms, which are even better at tricking our brains into thinking there is some object there.
 
  • #29
Schirillo said:
It's not "silly". You can see objects in depth with just one eye (cover one eye and notice that virtually nothing changes), however machines need stereo (or some form of triangulation). The incoming signal DOES NOT include depth information, it only contains wavelengths of light, not an additional signal as to where those wavelengths originated.

Schirillo has a point that can't be denied, though I'm not sure he's on the right track. There is is property of reflected light that hints at an object's distance: Focal length.

Our eyes will be in focus at a specific range of distance. An object six inches away will require a flexion of the eye's lens, whereas an object yards away will require the lens to relax. The brain does recognize this as a strong clue about the distance to the object.

Try this: put your hand one foot in front of your face and focus on it, closing one eye. The background of your living room will be out of focus. Now bring the living room walls into focus. There is most definitely an ability to tell nearby obects from distant objects.

(Of course, Schirillo is mistaken in that there's no reason why machines can't do this too...)



Another much more subtle and more conditional property of the imcoming light is contrast and colour. Due to the intervening air and impurities, distant objects such as mountains or skyscrapers will appear low in contrast and tinged in blue.
 
  • #30
DaveC426913 said:
Schirillo has a point that can't be denied, though I'm not sure he's on the right track. There is is property of reflected light that hints at an object's distance: Focal length.

That's an odd remark, since you have just denied the point he was making in what you quoted. You quoted the extract where he says "The incoming signal DOES NOT include depth information", and then go on to explain, correctly as others have done also, why his point is wrong.

Cheers -- sylas
 

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