Why is the band offset of an LED equal to the band gap?

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SUMMARY

The discussion centers on the relationship between the threshold voltage (V0) of LEDs and the band gap energy (Eg). The equation eV0 = Eg = hc/λ illustrates that V0 represents the energy offset between the conduction bands of p-type and n-type regions in a p-n junction, while Eg corresponds to the energy of emitted photons during electron transitions. The confusion arises from the assertion that the energy offset and band gap can be equal, which is debated in the context of the diode equation, suggesting that the concept of threshold voltage may not be applicable.

PREREQUISITES
  • Understanding of semiconductor physics, particularly p-n junctions
  • Familiarity with the concepts of band gap energy and photon emission
  • Knowledge of the diode equation and its implications
  • Basic grasp of Planck's constant and its role in quantum mechanics
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  • Research the diode equation and its relevance to LED operation
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Students and researchers in physics, electrical engineering, and materials science who are studying semiconductor devices, particularly those interested in the properties and behavior of LEDs.

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I am doing an experiment where we have to use the threshold voltage of LEDs to determine Planck's constant given the following relation

$$ eV_0 = E_g = \frac{hc}{\lambda} $$

where ## V_0 ## is the threshold voltage, ## \lambda ## is the wavelength of emitted light and ## E_g ## is the band gap.

After reading up, it is my understanding that ## eV_0 ## is the energy offset between the conduction band in the p-type and n-type regions of the p-n junction, which is caused by the electric field set up in the depletion layer. The right hand side is obviously the energy of the photon emitted by the LED when an electron transitions from the conduction to the valence band on one side of the junction. These two regions are separated by the band gap.

I am really struggling to see how the energy offset and the band gap can be equal like this. Any help would be much appreciated. Thank you.
 
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You are right, this is a dubious experiment. It is impossible to understand the results from physics alone. If you look at the diode equation, there is no threshold voltage.
 

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