Why Is There an Upper Limit to Photon Energy in Hydrogen's Emission Spectrum?

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why is there an upper limit to the photon energy that can be observed in the emission spectrum of the hydrogen atom?
 
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Because it corresponds to the difference of energy of the most energetic bound state of H, which is 0, and the ground state energy, which is a certain negative amount that I don't remember, something like 10 eV.
 
The ionization energy is 13.6 eV. Which corresponds to the light emitted by a H+ ion that absorbs an electron which drops immediately to ground state.
 
I am not sure if this falls under classical physics or quantum physics or somewhere else (so feel free to put it in the right section), but is there any micro state of the universe one can think of which if evolved under the current laws of nature, inevitably results in outcomes such as a table levitating? That example is just a random one I decided to choose but I'm really asking about any event that would seem like a "miracle" to the ordinary person (i.e. any event that doesn't seem to...
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