Work done by a gas with only pressure and volume

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Homework Help Overview

The discussion revolves around the work done by an ideal diatomic gas undergoing adiabatic compression, with specific initial and final pressures and volumes provided. Participants are exploring the relationship between pressure, volume, and the work done during this thermodynamic process.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the integration of pressure and volume to find work done, questioning the validity of using initial conditions versus final conditions in their calculations. They explore the relationship defined by the equation \( pV^{\gamma} = \text{const.} \) and its implications for determining final volume.

Discussion Status

The discussion is active, with participants raising questions about the assumptions underlying the use of initial and final conditions in their calculations. Some guidance has been offered regarding the use of the adiabatic condition, but no consensus has been reached on the specific application of these principles.

Contextual Notes

Participants are navigating the constraints of the problem, including the lack of certain variables like the number of moles and temperature change, which complicates their ability to fully resolve the work done by the gas.

PhizKid
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Homework Statement


An ideal diatomic gas undergoes an adiabatic compression. Its initial pressure and volume are 1.20 atm and 0.200 m^3 and its final pressure is 2.40 atm. How much work is done by the gas?

Homework Equations


W = -\int p \cdot dV

The Attempt at a Solution


So after integrating I got: W = -pV^{\gamma} \cdot \frac{{V_f}^{1 - \gamma} - {V_i}^{1 - \gamma}}{1 - \gamma}

My first question: How do I know what pV^{\gamma} is? Do I use the final pressure and volume for this constant term?

Second: How do I find V_f? I don't see any equation I can use to solve for it using only final pressure.
 
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PhizKid said:
My first question: How do I know what pV^{\gamma} is? Do I use the final pressure and volume for this constant term?
You know the initial pressure and the initial volume. Why not use those?

PhizKid said:
Second: How do I find V_f? I don't see any equation I can use to solve for it using only final pressure.
How about ##p V^\gamma = \mathrm{const.}##?
 
DrClaude said:
You know the initial pressure and the initial volume. Why not use those?
I wasn't sure if that was a valid substitution. How do you know you are allowed to use the initial conditions and not something else? Can I use either initial or final conditions (provided I know the final conditions) for that substitution?

DrClaude said:
How about ##p V^\gamma = \mathrm{const.}##?
Oh...is ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}##? Or are you implying something else? If ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}## is true, how do you know it's true? I don't see why we can assume the initial adiabatic pressure and volume conditions must equal the final ones.
 
Last edited:
PhizKid said:
I wasn't sure if that was a valid substitution. How do you know you are allowed to use the initial conditions and not something else? Can I use either initial or final conditions (provided I know the final conditions) for that substitution?


Oh...is ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}##? Or are you implying something else? If ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}## is true, how do you know it's true? I don't see why we can assume the initial adiabatic pressure and volume conditions must equal the final ones.
Both points I was making rest on the same idea: during an adiabatic process, ##V^\gamma p = \mathrm{const.}## ##\gamma## is not called the adiabatic exponent for nothing! You should find the proof for this in any thermodynamics textbook. The conclusion is that you can use the initial conditions as well as the final conditions in the equation for work, and the initial conditions you already have. Also, you can use ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}## to find ##V_f##.
 
Thank you very much DrClaude
 
PhizKid said:
... How much work is done by the gas?


Homework Equations


W = -\int p \cdot dV
For work done BY the gas, W = ∫PdV. For work done ON the gas W = -∫PdV

You can also solve this problem by using W = -ΔU = nCVΔT (since Q = 0). You cannot determine ΔT or n but you can determine nΔT quite easily.

AM
 

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