Writting total energy from temperature

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Homework Help Overview

The discussion revolves around deriving an expression for total energy in terms of temperature and particle number, specifically focusing on the relationship between energy, temperature, and entropy in a thermodynamic context.

Discussion Character

  • Exploratory, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to derive the total energy expression E(T,N) = 3/2*N*hbar*omega*coth(hbar*omega/(2*kT)) and has formulated a relationship for temperature based on entropy differentiation. Participants explore how to manipulate exponential expressions to isolate energy and connect them to hyperbolic functions.

Discussion Status

Participants are actively engaging with hints and suggestions to manipulate equations, with some expressing confusion about isolating variables and transforming expressions into the desired form. There is a collaborative effort to clarify the relationships between the variables involved.

Contextual Notes

Participants are working under the constraints of homework guidelines, which may limit the extent of direct assistance provided. There is an ongoing exploration of assumptions related to the definitions and relationships between energy, temperature, and entropy.

mhellstrom
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Hi all,

I have to compute the entropy, temperature and show that the total energy can be written as

E(T,N) = 3/2*N*hbar*omega*coth(hbar*omega/(2*kT))

I have found that the temperature can be written as

1/T = k/(hbar*omega)*ln([E/N*hbar*omega+3/2]/[E/N*hbar*omega-3/2])

by differentiating the entropy with respect to E. Next, I would like to show that the energy can be written as shown above:

1. (hbar*omega)/(k*T) = ln([E/N*hbar*omega+3/2]/[E/N*hbar*omega-3/2])

2. exp((hbar*omega)/(k*T)) = ([E/N*hbar*omega+3/2]/[E/N*hbar*omega-3/2])

but this last term doesn't give me any hyperbolic cotangens?

Any help or suggestions appreciated. Thanks in advance

Best
M
 
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Hi mhellstrom! :smile:

Hint: cothx = (e2x + 1)/(e2x - 1) :wink:
 


thanks - I have tried to isolate E but cannot. I can see how my expression to the right looks like coth... Could u guide me one more step I hope that is all I need :smile:
 
mhellstrom said:
thanks - I have tried to isolate E but cannot. I can see how my expression to the right looks like coth... Could u guide me one more step I hope that is all I need :smile:

Hi mhellstrom! :smile:

Hint: if e2x = A/B,

then (e2x + 1)/(e2x - 1) = (A + B)(A - B) :wink:
 
did you mean
(A+B)/(A-B) ?

A = E and B = 3/(2N)*hbar*omega
So insert this into the equation

exp (hbar*omega/(kT))= (A/B +1) / (A/B-1)
exp (hbar*omega/(kT))= (A+B)/(A-B)

I am still confused how to get A isolated and how to transform the right hand side into coth?

How to proceed

Thanks very much

Best
M
 
I'm not following you. :confused:

Apply (A+B)/(A-B) to:
mhellstrom said:
2. exp((hbar*omega)/(k*T)) = ([E/N*hbar*omega+3/2]/[E/N*hbar*omega-3/2])
 
Hi

What I mean is that I have rewritten the expression as

exp((hbar*omega)/(k*T)) = (E+3/2*N/(hbar*omega)/(E-3/2*N/(hbar*omega)

which is (A+B)/(A-B) I presume...than I would like to isolate E... but here I am still lost

Thanks for helping me...

Best regards
 
mhellstrom said:
… exp((hbar*omega)/(k*T)) = (E+3/2*N/(hbar*omega)/(E-3/2*N/(hbar*omega)

which is (A+B)/(A-B) I presume...than I would like to isolate E... but here I am still lost

erm … if that's (A+B)/(A-B), then what is A/B? :redface:
 
u are right - I have not understood that hint;

A/B = exp(hbar*omega/(4*k*T)) / exp(-hbar*omega/(4*k*T))

is A/B? but how one can rearrange it to coth(X) I still don't understand...
 
  • #10
cothx = (exp2x + 1)/(exp2x - 1)

mhellstrom said:
u are right - I have not understood that hint;

A/B = exp(hbar*omega/(4*k*T)) / exp(-hbar*omega/(4*k*T))

is A/B? but how one can rearrange it to coth(X) I still don't understand...

Put A = E, B = 3/2*N/(hbar*omega) :smile:
 
  • #11
ahhh - I did that later: A = E, B = 3/2*N/(hbar*omega). Ok I see how to solve it now Thanks u very much couldn't see the forest for trees ;-)

Thanks for the hint and yr help all the best

M
 

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