Ionization Enthelpy, Electron Gain Enthelpy and Electron Affinity

AI Thread Summary
Ionization Enthalpy is the energy needed to remove an electron from an atom, while Electron Gain Enthalpy is the energy required to add an electron. Electron Affinity is often described as the negative of Electron Gain Enthalpy, indicating that when an electron is added, energy can be released, resulting in a negative value. The discussion raises a question about why Electron Gain Enthalpy can have both negative and positive values, whereas Ionization Enthalpy consistently requires energy input. Understanding these concepts clarifies the thermodynamic principles governing electron interactions in atoms.
physics kiddy
Messages
135
Reaction score
1
Ionization Enthalpy is defined as the amount of energy required to remove an atom's electron (can be valence or consecutive) ... this definition doesn't sound so complex. The definition of Electron Gain Enthalpy - it is the amount of energy required to add an electron. But, what is Electron Affinity ? One book says it is the negative of electron gain enthalpy. Then, there is some thermodynamic rule saying negative value of electron gain enthalpy indicates that energy has to be supplied and positive value indicates energy is released. My question is how can electron gain enthalpy have both negative and positive values but ionisation enthalpy doesn't have. Also please explain what the differnece between affinity and gain enthalpy is.
Thanks in advance ...
 
Physics news on Phys.org
i.e. in the case of electron gain enthalpy energy is released and in ionization enthalpy energy is gained.
 
This is from Griffiths' Electrodynamics, 3rd edition, page 352. I am trying to calculate the divergence of the Maxwell stress tensor. The tensor is given as ##T_{ij} =\epsilon_0 (E_iE_j-\frac 1 2 \delta_{ij} E^2)+\frac 1 {\mu_0}(B_iB_j-\frac 1 2 \delta_{ij} B^2)##. To make things easier, I just want to focus on the part with the electrical field, i.e. I want to find the divergence of ##E_{ij}=E_iE_j-\frac 1 2 \delta_{ij}E^2##. In matrix form, this tensor should look like this...
Thread 'Applying the Gauss (1835) formula for force between 2 parallel DC currents'
Please can anyone either:- (1) point me to a derivation of the perpendicular force (Fy) between two very long parallel wires carrying steady currents utilising the formula of Gauss for the force F along the line r between 2 charges? Or alternatively (2) point out where I have gone wrong in my method? I am having problems with calculating the direction and magnitude of the force as expected from modern (Biot-Savart-Maxwell-Lorentz) formula. Here is my method and results so far:- This...
Back
Top