I want to know the microscopic mechanism of electric polarition of amorphous

In summary, electric polarization in amorphous materials is the separation of charges within the material when an external electric field is applied. It is different from crystalline materials due to the lack of long-range order, which results in a more random and isotropic polarization. The microscopic mechanism involves the movement of charge carriers in response to an external field. The presence of defects can affect polarization, and understanding this mechanism has various technological applications.
  • #1
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Who can tell me the microscopic mechanism of electric polarition of amorphous,such as Si3N4 or SiO2.Which dominates the permittivity of amouphors,is it Eletronic polarization,orientational polarization,Atomic ploraization or something others?thank you.
 
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  • #3


I can provide you with some information on the microscopic mechanism of electric polarization in amorphous materials such as Si3N4 or SiO2. Electric polarization is the process by which a material acquires a dipole moment in an electric field, causing a separation of positive and negative charges.

In amorphous materials, the permittivity is mainly dominated by electronic polarization, which is the displacement of electrons within the material in response to an electric field. This is due to the lack of a regular crystal structure in amorphous materials, making it difficult for the molecules to align and contribute to orientational or atomic polarization.

However, in some cases, orientational polarization can also play a role in the permittivity of amorphous materials. This is the alignment of molecules or dipoles in response to an electric field, which can occur in materials with a certain degree of molecular orientation.

In summary, the dominant mechanism of electric polarization in amorphous materials is electronic polarization, but orientational polarization can also contribute in some cases. Other factors such as atomic polarization may also play a role, but to a lesser extent. I hope this helps to answer your question.
 

1. What is electric polarization in amorphous materials?

Electric polarization in amorphous materials refers to the separation of positive and negative charges within the material when an external electric field is applied. This creates an induced dipole moment, resulting in a net polarization of the material.

2. How is electric polarization of amorphous materials different from crystalline materials?

The main difference between electric polarization in amorphous and crystalline materials is the lack of long-range order in amorphous materials. In crystalline materials, the arrangement of atoms is highly structured, resulting in a well-defined polarization direction. In amorphous materials, the lack of order results in a more random and isotropic polarization.

3. What is the microscopic mechanism behind electric polarization in amorphous materials?

The microscopic mechanism of electric polarization in amorphous materials involves the movement of charge carriers, such as electrons or ions, in response to an external electric field. This movement results in the separation of charges and the creation of an induced dipole moment, leading to the net polarization of the material.

4. How does the presence of defects in amorphous materials affect electric polarization?

The presence of defects, such as impurities or structural irregularities, can disrupt the movement of charge carriers and hinder the formation of an induced dipole moment. This can result in a decrease in electric polarization or even a reversal of polarization direction in amorphous materials.

5. What are the applications of understanding the microscopic mechanism of electric polarization in amorphous materials?

Understanding the microscopic mechanism of electric polarization in amorphous materials is crucial for various technological applications, such as in the development of electronic devices, capacitors, and sensors. It can also aid in the design of new materials with specific electric properties, such as high dielectric constant or low dielectric loss. Additionally, it can provide insights into the behavior of amorphous materials in various environments, such as under extreme temperatures or in the presence of radiation.

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