Special cases of the Schroedinger Eq?

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In summary, the lecture discusses the simplification of the Schrödinger equation for time-invariant and spatially-invariant potentials. The equation can be simplified to -k^2ψ for the latter case, but only if the potential is constant. If the potential is non-constant, the kinetic energy V-E becomes a function of position, represented as k(x). This was not made clear in the lecture, leading to confusion.
  • #1
ManDay
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According to the lecture I'm hearing the SE can be simplified for the cases of a timeinvariant potential and a constant potential:

Time invariant

[itex]\frac{\partial^2\psi}{\partial x^2} = 2\frac m{\hbar^2}(V(x)-E)\psi[/itex].

Then, the lecture states that for the case of the potential being not just time but also spatially invariant it can be simplified to

[itex]\frac{\partial^2\psi}{\partial x^2} = -k^2\psi[/itex]

My question is, why this is said to be possible, only if the potential is constant. Given the term [itex]V(x) - E[/itex] we can conclude that [itex]V(x) - E = E_{kin}[/itex] and hence [itex]\frac12\hbar^2\frac{k^2}m[/itex]

Thanks
 
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  • #2
If the potential is non-constant then the kinetic energy V-E is once again a function of position. Your last result is not a function of position.
 
  • #3
Call it k(x) Then it is a function of position.

nvm replying, I got the "idea" and I've to blame it on the lecture that this wasn't clear.
 
Last edited:

Related to Special cases of the Schroedinger Eq?

1. What are the special cases of the Schroedinger Equation?

The special cases of the Schroedinger Equation include the free particle, the infinite square well, the harmonic oscillator, the finite square well, and the delta function potential. These are commonly used to study quantum mechanics and the behavior of particles in different potential energy scenarios.

2. How does the free particle differ from the other special cases?

The free particle is the simplest special case of the Schroedinger Equation. In this scenario, the particle has no potential energy and can move freely without any external forces acting on it. This is in contrast to the other special cases where there is a potential energy present, causing the particle to behave differently.

3. What is the significance of the infinite square well in quantum mechanics?

The infinite square well is a commonly used model in quantum mechanics to study the behavior of particles in a confined space. It is an idealized scenario where the potential energy is infinite within a certain region and zero outside of it. This allows for the study of particle behavior in a bounded system, which has implications in understanding atomic and molecular structures.

4. How does the harmonic oscillator differ from the other special cases?

The harmonic oscillator is a special case where the potential energy is proportional to the square of the distance from the equilibrium point. This leads to a sinusoidal wave function and is commonly used to study the behavior of particles in a vibrating or oscillating system, such as atoms and molecules.

5. Can the special cases of the Schroedinger Equation be applied to real-world scenarios?

While the special cases of the Schroedinger Equation are idealized models, they can be used to approximate real-world scenarios and provide insights into the behavior of particles in different potential energy scenarios. They have been successfully applied in various fields such as chemistry, material science, and quantum computing.

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