How do we know a state function will stay normalized?

In summary, according to Schrodinger's equation, the state function must change with time. However, after normalizing the state function, it will remain normalized due to the unitarity of the evolution operator. This means that the probability of observing a particle in a certain location in the universe will not suddenly disappear, as particles are conserved in non-relativistic processes. The actual proof of this concept can be found in Griffith's introduction to quantum mechanics.
  • #1
esradw
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0
According to Shrodinger Equation, The state function must change with time, soI wonder how do we know that after we normalize this state function, it will stay normalized ?

Thanks
 
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  • #2
I don't remember the actual proof, but the notion that the wave function must stay normalized is fairly logical.

Think of it this way... in a non relativistic process matter must be conserved... The fact that the wave function is normalized means that there is a probability to observe the particle somewhere in the universe. Given that it's here one minute (ie in our universe) we would expect it to remain within our observable universe in the next.

All it's saying is that particles don't suddenly disappear.

I believe griffith's intro to QM has the actual proof.
 
  • #3
Schrodinger's equation can be expressed as an unitary transform from a state a t=0 to a state t=t' and unitary transforms leave the inner product of wavefunctions unchanged. So if the initial wave function was normalized then evolution under the Schrodinger equation will lead to another wavefunction which is also normalized.

This is not true for the process of measurement since it cannot be represented by a unitary transform.
 
  • #4
Consider [tex]\frac{d}{dt}\left(\psi\psi^{\ast}\right)[/tex] using Schrodinger's Equation and if memory serves it drops out fairly easily.
 
  • #5
This is just a copy/paste of post I made in another thread..

When solving the SE by the method of separation of variables, we find that the time dependant part of the solution is [itex]\exp{iEt/\hbar}[/itex], and the position dependant part satisfies the time-independant SE. Denote [itex]\psi(x)[/itex] the solution to the time independant SE for a given potential. Then the general solution to the SE is [itex]\Psi(x,t)=\psi(x)e^{iEt/\hbar}[/itex], and according to the Born interpretation, [itex]\Psi \Psi^*[/itex] is a probability density function for the position of the particle. But [itex]\Psi \Psi^* = \psi\psi^*[/itex]. I.e. the probability density is is time independant!

From there, showing that the normalisation constant is time-independant is just one step away.
 
  • #6
[tex] \frac{d}{dt}\left(\langle \psi(t),\psi(t)\rangle\right) =0 \Leftrightarrow \frac{d\psi(t)}{dt}=\frac{1}{i\hbar}\hat{H}\psi(t) \ ,\ \forall \psi(t)\in D(\hat{H}) [/tex]

Daniel.
 
  • #7
The normalisation remains because of the unitarity of the evolution operator.
The operator U = exp(H t /i hbar) preserves the normalisation because H is hermitian.
This is easy to check by developping
<phi(t)|phi(t)> = <phi(0)|Ut U|phi(o)>​
for small time steps.
Therefore is applies also for time-dependent hamiltonians.

Michel
 
Last edited:

1. What is a state function?

A state function is a mathematical function that describes the state of a physical system. It is used in quantum mechanics to represent the state of a particle or system, and it contains all the information needed to predict the behavior of the system.

2. Why is it important for a state function to be normalized?

Normalization is important for a state function because it ensures that the total probability of finding a particle in any possible state is equal to 1. This is necessary for the function to accurately represent the state of the system and make meaningful predictions.

3. How do we normalize a state function?

To normalize a state function, we divide the function by the square root of the integral of the function multiplied by its complex conjugate. This ensures that the total probability is equal to 1.

4. What happens if a state function is not normalized?

If a state function is not normalized, it means that the total probability of finding a particle in any possible state is not equal to 1. This can lead to incorrect predictions and is not a valid representation of the state of the system.

5. Can a state function become unnormalized over time?

No, a state function will always remain normalized as long as the system is isolated and not affected by external factors. However, if the system is disturbed or measured, the state function may change and need to be renormalized to accurately represent the new state of the system.

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