What is Molecules: Definition and 560 Discussions

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. S

    Diatomic molecules bond energies

    The bond enthalpies for these bonds are: C-C 347 kJ/mol C-N 276 kJ/mol C-O 351 kJ/mol Why is carbon-nitrogen bond enthalpy lower? What factor makes that? And also the halogens bond enthalpies: F-F 157 kJ/mol Cl-Cl 243 kJ/mol Br-Br 193 kJ/mol I-I 151 kJ/mol Why has fluorine lower enthalpy? I...
  2. electricspit

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    Homework Statement https://ia701205.us.archive.org/11/items/Mechanics_541/LandauLifshitz-Mechanics.pdf Page 72 of the book itself, but Page 81 of the PDF. Problem 1. Homework Equations See Section 24 of the book. The Attempt at a Solution So far I have completed and...
  3. Entanglement

    Collision between gas molecules with liquid molecules

    What happens when a gas molecule collides with a liquid molecule at the microscopic level ?
  4. S

    Software for atomic orbitals oveplap in molecules

    I would be most grateful for some tips of interactive software, which shows the hybridized atomic orbitals overlapping in the molecule (I don't mean resulting molecular orbitals but atomic orbitals of which overlapping forms MO). And does this works also in Mathematica?
  5. Q

    Chemistry Bond Angles in Trigonal Bipyramidal Molecules

    Homework Statement What are the number of different bond angles for the isomer of F_{3}PCl_{2} with each chlorine equatorial? What about for the isomer of BrPF_{4} with the bromine axial? According to the key the the first molecule has 5 unique bond angles. Homework Equations Trigonal...
  6. L

    Help with rms speed of gas when molecules are doubled

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  7. Z

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    If there is a molecule that is negatively charged after gaining an electron and it only needs one hydrogen to be hydrogenated, in the presence of H2 will one of the hydrogen leave the hydrogen pair to hydrogenate the negatively charged molecule? Or does the hydrogen have to be already separated...
  8. U

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  9. K

    Collisional excitation of diatomic molecules

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  10. M

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    I read in my Chemistry workbook that: "At higher temperatures, vapour pressure increases as more energy is provided to the liquid molecules, allowing them to escape into the gas phase." At the boiling point, all energy is gone into breaking bonds and to convert liquid phase molecules into...
  11. nukeman

    What forces hold molecules together?

    Does the strong nuclear force and the electromagnetic force plat into it at all, as in their role in holding atoms together?
  12. T

    Software to find similarity of two molecules

    I have two files with atomic coordinates for the same generated strucutre (cycle made of eight sulphur atoms), but produced by two different progams (so that output files have different coordinates supposedly connected by translation/rotation). Is there some kind of software to compare the two...
  13. A

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    Do molecules have intrinsic magnetic fields to them? Let's say you have a water molecule H20. Would the oxygen have a field due to the orientation of it's electrons, and possibly the hydrogens fields act to reduce that field? I'm just curious.
  14. A

    Deducing Number of Molecules in a Scuba Tank

    Homework Statement A scuba tank has a volume of 2800cm3. For very deep dives, the tank is lled with 50% (by volume) pure oxygen (O2) and 50% pure helium (He). The molar mass of helium is 4 g mol/1, and for oxygen is 32 g mol/1. How many molecules are there of each type in the tank if it is...
  15. F

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  16. curiousKevo

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    Estimate the probability that in a room of volume V, all the N molecules of air are found in volume \frac{3V}{4} and none at all in the reaining volume V/4 My take to the solution is Pr of finding N molecules in \frac{3V}{4} : \frac{N}{3V/4}= \frac{4N}{3V} Pr finding none in V/4...
  17. J

    Can elements replace Hydrogen in polar molecules & act similarly?

    Today in 9th grade ADV Biology, we learned about how the two Hydrogen atoms in a Water molecule are relatively positive compared to the Oxygen atom. This is because the Oxygen's pull on Hydrogen's electron is greater than the Hydrogen's, or that its Electronegativity is greater. This unequal...
  18. LarryS

    Molecules Structure as Planar Graphs?

    I have read that the structure of almost all organic molecules can be represented visually as Planar Graphs, i.e. 2-dimensional lattice-like structures consisting of nodes (points) connected by lines in which no lines cross. From the perspective of Physical Chemistry, does anybody know why this...
  19. N

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    I have read that relaxation of a rotational or vibrational mode in gases occurs through collisions of molecules , transferring energy of an excited vibrational mode into heat. But isn't it possible that an excited vibrational mode in molecules relaxes directly by emission of radiation...? I...
  20. K

    Exploring Length Contraction: Mechanisms and Implications in Relativistic Speeds

    Given that molecules, atoms, protons, and neutrons are overwhelmingly space (i assume quarks and electrons are more than just fields), when an object reaches relativistic speeds, is length contraction the result of a decrease in the geometric space within the molecules, or is it a decrease in...
  21. B

    Behavior of Air Molecules when Heated

    Homework Statement Some gas is heated in a sealed container. How do the average distance between the gas molecules, and the frequency of the molecules' collision with the walls, change when the container (A) has a fixed volume, and (B) is allowed to expand outwards? The attempt...
  22. V

    Can We See Atoms and Molecules Without High Powered Microscopes?

    Hi guys, I hope you don't mind me posting here, I am doing some research into atoms, molecules and microscopes. I have no knowledge of physics, the quantum world or microscopy so if my questions seem silly, please look past that and help me. Thank you I have two questions. Is there a way...
  23. S

    Chemistry Average distance between gas molecules

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  24. A

    I'm pretty sure these molecules are polar

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  25. Hyo X

    Larger molecules have smaller HOMO-LUMO Gaps?

    Is it true that in general, larger molecules will have smaller HOMO-LUMO gaps? In this case consider that we are comparing long vs short saturated molecules, and long vs. short conjugated molecules.
  26. B

    Schrodinger equation molecules

    How do I write a full Schrodinger equation, pre-approximation, for a mixture? Let's say 75% H2 and 25% He by number of particles. I already know the form and very basic applications of the Schrodinger equation and the Hamiltonian. What I want to know is, the specifics, such as how to specify...
  27. R

    Memory Allocation problems in Gaussian09 for organic molecules

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  28. P

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  29. A

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  30. B

    Find Symmetry in Molecules: NMR Spectra & 3D Structures

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  31. tsuwal

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    Homework Statement Look at the image please. The image shows 3 pairs of compounds. Explain why the first two are not chiral but the last one is chiral. Homework Equations Ar means Aromatic ring Aquirais means aquiral Quirais means chiral The Attempt at a Solution...
  32. S

    Dehydration in organic molecules

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  33. A

    Determining the equivalent weight of molecules.

    What is the equivalent weight of ozone molecule? I mean how can I find out the equivalent weight of molecules? Is it same as the equivalent weight of element? For example, FeCl3 ,what will be the equivalent weight of chlorine ?
  34. E

    Finding what fraction of molecules have speeds over a certain value

    Homework Statement A sample of oxygen gas with molar mass 32 g/mol contains 5.0 moles and is at a temperature of 500 K. How many moles of the gas have speeds between 375 m/s and 380 m/s? Homework Equations Maxwell Boltzmann Distribution: f(v) = 4\pi[\frac{M}{2pi RT}]^(3/2) * v^2 *...
  35. adjacent

    Kinetic theory and gas molecules

    The kinetic theory states that the gas molecules are randomly colliding with each other and with the wall of the container with high speed.The area of each molecule is very less and as they are moving with high speed,they exert great force. since the pressure is force/area , the pressure should...
  36. shounakbhatta

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    Hello, The formula for average kinetic energy of molecule is: k=3/2KT. Can anyone please explain the derivation without using calculus? Thanks, -- Shounak
  37. S

    Boyle's Law and collisions by the ideal gas molecules on the container

    When we use Boyle's Law it means that as pressure increases the volume of the container would decrease. In my notes they stated that if I were to halve the volume there would be two times the number of collisions per second which implies that the force exerted is doubled. But why is this so? I...
  38. M

    Simulating Molecules: Can We Simulate Complexity?

    We can simulate physical movements of atoms and molecules and how they interact with many software like ascalaph or abalone. But can we one day simulate complex interaction of molecules like the interactions that happens inside a simple organism like a simple bacteria? And going further, can...
  39. W

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    When making the Morse Potential graphs of diatomic molecules going through a transition, the excited state sometimes has a different equilibrium bond length. A visual example is here: http://en.wikipedia.org/wiki/File:Franck-Condon-diagram.png I was wondering how the average bond length of...
  40. T

    How to draw Lewis structure of molecules with N

    Many times, I find it hard to draw correct Lewis structure of molecules with nitrogen. For instance: the Lewis structure of H2CNN. I thought it should be double bond between C and N and single bond between N and N, like this: But actually it's not. I have done many problems like this wrong...
  41. C

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    I'm way outside my realm of knowledge here so perhaps I need some help polishing my question or the concepts behind it. Thank you for your patience. Does the orientation of circularly polarized light (CPL) as a reaction mechanism influence the chirality of the molecule in a general manner...
  42. B

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  43. F

    Exploring the Role of Strong Magnetic Fields in Moving Water Molecules

    Can a strong magnetic field move water molecules because it is a polar molecule. How strong does the field need to be?
  44. S

    What prevents molecules from being too close to each other?

    Homework Statement When we have a liquid, there are Van der Waals forces of attraction in between each molecule. Hence, the negatively charged electron cloud would be attracted to the positive nucleus of the neighboring molecule. However, there seems to be a gap in between the molecule (least...
  45. jaketodd

    Destabilizing Molecules Through Electron Rearrangement?

    By changing the arrangement of electrons in a molecule's energy levels (without adding or removing any electrons), can the molecule become destabilized or come apart? An example or two would really help. Thanks, Jake
  46. V

    Auto correlation function for water molecules in a box

    I have simulated a box water molecules (1500 water molecules) using molecular dynamics method in NpT ensemble. I got the time auto-correlation function (C(t) vs t, time) where its function line is parallel to x-axis. Which means the C(t) is zero. I understand the water molecules are...
  47. S

    Finding the average height, z, of molecules in the box

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  48. Greg Bernhardt

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  49. S

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    If molecules generally move at sound speed, given they are accelerated at Mach 1, does this mean there are less arbitrary collisions? or less collisions in general and more molecules move in the direction of mach 1 speed??
  50. D

    Chemistry About the dispersion force in polar molecules

    Homework Statement Hi, dispersion force exists in non-polar molecules due to instantaneous dipole. In polar molecule,the intermolecular force is the sum of dipole-dipole force and dispersion force. Polar molecules have permanent dipoles,this enables the oppositely charged end of molecules...
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