Can Raman spectroscopy identify every substance?

In summary, raman spectroscopy has the potential to identify any substance, as all point groups have active Raman modes. However, for substances with very small Raman modes, the magnitude may not be large enough to measure. This mainly applies to bound substances with rotational and vibrational states, such as molecules and solids. It may be difficult to obtain Raman spectra for substances in liquid state, and monatomic gases like noble gases may be completely transparent to Raman spectroscopy unless they have very-low-energy electronic transitions.
  • #1
David lopez
257
3
Can raman spectroscopy identify any substance or are there certain
Substances raman spectroscopy cannot identify?
 
Physics news on Phys.org
  • #2
in theory, yes. All point groups have active Raman modes, but the magnitude may not be large enough to measure.
 
  • #3
What substances have raman modes
Too small to measure?
 
  • #4
If somebody built a raman spectroscopy, is there any reason 5 milliwatts would be inadequate for this
Application?
 
  • #5
Dr Transport said:
in theory, yes. All point groups have active Raman modes, but the magnitude may not be large enough to measure.

When you write "In theory, yes", will the OP have realized that you're answer applies only to bound substances with rotational and vibrational states: mainly molecules and solids (point groups)?

Obtaining raman spectra in liquid state studies can be difficult: https://www.researchgate.net/post/How_to_prepare_liquid_sample_for_Raman_spectrometer_to_get_good_spectrum

But unless they display very-low-energy electronic transitions, I would expect monatomic gases such as noble gases to be completely transparent to raman spectroscopy (except when adsorbed onto a surface, in which case such spectra have been observed, e.g. https://www.semanticscholar.org/pap...hita/ce681015459750bb4dfc4882d3d125b2b5869046).

Regards - P
 

1. Can Raman spectroscopy identify every substance?

No, Raman spectroscopy cannot identify every substance. It is most effective for identifying substances with polarizable bonds, such as organic molecules.

2. How does Raman spectroscopy work?

Raman spectroscopy works by shining a laser onto a sample and measuring the scattered light. The scattered light is then analyzed to determine the vibrational frequencies of the molecules in the sample.

3. What are the advantages of using Raman spectroscopy?

Some advantages of using Raman spectroscopy include its non-destructive nature, its ability to analyze samples in various states (solid, liquid, gas), and its sensitivity to small changes in molecular structure.

4. Are there any limitations to Raman spectroscopy?

Yes, there are limitations to Raman spectroscopy. It may not be able to identify substances with similar molecular structures, and it is not as sensitive as other spectroscopic techniques, such as infrared spectroscopy.

5. How is Raman spectroscopy used in scientific research?

Raman spectroscopy is used in various fields of scientific research, including chemistry, biology, and materials science. It can be used to identify unknown substances, study chemical reactions, and analyze the composition of materials.

Similar threads

Replies
31
Views
5K
  • Other Physics Topics
Replies
15
Views
4K
  • Quantum Physics
Replies
2
Views
820
Replies
1
Views
3K
  • Introductory Physics Homework Help
Replies
7
Views
1K
Replies
1
Views
710
  • Atomic and Condensed Matter
Replies
1
Views
1K
  • Atomic and Condensed Matter
Replies
13
Views
3K
  • Other Physics Topics
Replies
6
Views
2K
  • Materials and Chemical Engineering
Replies
1
Views
899
Back
Top