Derivation of Thermodynamic Relations

Engineering
Thread starter lohboys
Start date Oct 19, 2019
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Derivation Relations Thermodynamic

In summary, the basic thermodynamic relations include the first and second laws of thermodynamics, the Maxwell relations, and the Gibbs-Duhem equation. They describe the behavior of thermodynamic systems and the relationships between different properties. The first law of thermodynamics is derived from the principle of conservation of energy, while the Maxwell relations are derived from the total differential of a property. The Gibbs-Duhem equation is a fundamental relation that describes the relationship between changes in chemical potential, temperature, and pressure. These relations are used in practical applications such as designing heat engines and studying phase transitions.

Oct 19, 2019

lohboys

Homework Statement: I'm trying to derive a thermodynamic relation in terms of P,V,T,Cp,Cv and was wondering if my working was correct. I am trying to derive (dG/dV) at constant temperature

Relevant Equations: dG= -SdT + VdP

dG= -SdT + VdP ... now dividing by dV holding temperature constant
(dG/dV)T = -S (dT/dV)T + V (dP/dV)T ... now dT and constant temperature cancel out
final answer:
(dG/dV)T = V (dP/dV)T

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Oct 20, 2019

mitochan

Hi. The mathematics seems all right.

1. What is the derivation of thermodynamic relations?

The derivation of thermodynamic relations is the process of mathematically deriving equations that relate different thermodynamic properties, such as temperature, pressure, and volume, to each other. These relations are based on the fundamental laws of thermodynamics and are used to understand and predict the behavior of thermodynamic systems.

2. Why is the derivation of thermodynamic relations important?

The derivation of thermodynamic relations is important because it allows us to understand and analyze the behavior of thermodynamic systems using mathematical equations. These equations can be used to make predictions and solve problems related to energy transfer, phase changes, and other thermodynamic processes.

3. What are some common thermodynamic relations?

Some common thermodynamic relations include the ideal gas law, the first law of thermodynamics, and the second law of thermodynamics. Other important relations include the Maxwell relations, the Clausius-Clapeyron equation, and the Gibbs-Duhem equation.

4. How are thermodynamic relations derived?

Thermodynamic relations are derived using mathematical techniques such as calculus and algebra. These techniques are applied to the fundamental laws of thermodynamics and other thermodynamic equations to derive new relationships between thermodynamic properties.

5. What are some real-world applications of thermodynamic relations?

Thermodynamic relations have many real-world applications, including in the design of engines and power plants, the study of atmospheric processes, and the development of new materials and technologies. They are also used in many industrial processes, such as refrigeration, chemical reactions, and energy production.