Question about a cubic crystal and its parameters

In summary, the conversation discusses finding the radius of A in a crystal structure problem involving CsCl. The solution involves using the diagonal of the cube and the radius ratio to find the radius of A, which is determined to be 0.124nm.
  • #1
Clara Chung
304
14

Homework Statement


27.png


Homework Equations

The Attempt at a Solution


28.png

So i got the answer by finding the diagonal of the square and then find the radius of A.
([(2x0.17)2 ]x2 )1/2 = 2a + 2x0.17
And find out a= 0.14 nm , however the answer is 0.124nm, please help
 

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  • #2
I think this is a 3D problem.
 
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  • #3
Clara Chung said:

Homework Statement


View attachment 224603

Homework Equations

The Attempt at a Solution


View attachment 224604
So i got the answer by finding the diagonal of the square and then find the radius of A.
([(2x0.17)2 ]x2 )1/2 = 2a + 2x0.17
And find out a= 0.14 nm , however the answer is 0.124nm, please help
The number of nearest neighbors are 8, it is CsCl structure:

upload_2018-4-24_18-4-14.png

In your drawing, the number of nearest neighbors are 6.
 

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  • #4
Clara Chung said:

Homework Statement


View attachment 224603

Homework Equations

The Attempt at a Solution


View attachment 224604
So i got the answer by finding the diagonal of the square and then find the radius of A.
([(2x0.17)2 ]x2 )1/2 = 2a + 2x0.17
And find out a= 0.14 nm , however the answer is 0.124nm, please help
Yes, the crystal structure can be simply identified identical to the CsCl where Cl- forms a cubic lattice and Cs+ occupies the body centers(cubic voids). Now you can easily use the radius ratio(r+/r-) for cubic void(here for smallest value of A use lower limit of the radius ratio range) to find out the radius of A
hint: here it is assumed that B forms the lattice and A occupies the voids
Hope that helps... [emoji4]
images%20(1).jpeg
 

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  • #5
Thanks everyone for the pictures and information. I got the answer by using the diagonal of the cube. [[3x(2x0.17)2]1/2 - 2x(0.17)]/2 = 0.124
 

1. What is a cubic crystal?

A cubic crystal is a type of crystalline solid that has a three-dimensional lattice structure consisting of repeating unit cells. It is characterized by its cubic symmetry, meaning that all of its crystal faces are equal in size and shape. Examples of cubic crystals include common salt (NaCl) and diamond (C).

2. What are the parameters of a cubic crystal?

The parameters of a cubic crystal refer to its lattice constants, which are the lengths of the edges of the unit cell. In a cubic crystal, all three lattice constants are equal, making it a cube. These parameters are important in determining the physical and chemical properties of the crystal.

3. How are the parameters of a cubic crystal measured?

The parameters of a cubic crystal can be measured using techniques such as X-ray diffraction or electron microscopy. These methods involve analyzing the diffraction patterns produced by the crystal to determine the spacing between the lattice planes, which can then be used to calculate the lattice constants.

4. What is the significance of cubic symmetry in a crystal?

Cubic symmetry in a crystal indicates that the crystal has a high degree of order and uniformity. This symmetry allows for the crystal to have predictable physical and chemical properties, making it useful in many applications.

5. Can cubic crystals have defects or imperfections?

Yes, cubic crystals can have defects or imperfections in their lattice structure, just like any other type of crystal. These defects can occur during the crystal's formation or due to external factors, and can affect the crystal's properties. However, cubic crystals are known for their high structural stability, making them less prone to defects compared to other crystal structures.

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