Question about reversible adiabatic expansion

In summary, there is a difference between how Cv is measured experimentally and how it is used to solve problems. In a constant volume experiment, the amount of work done is zero, so ΔU=Q. To get the change in internal energy as a result of changing only the temperature, we measure the heat added in a constant volume experiment. The heat capacity Cv is defined to be equal to the (∂U/∂T) at constant V. This is how we measure Cv experimentally. However, for an ideal gas, we know that the internal energy U is a function only of T, but not of specific volume V. So we can then use the measured value of Cv from the constant volume experiment to calculate
  • #1
hybro
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Hello guys, I have some troubles to understand a reversible adiabatic expansion.
we have dq=0 and dw=-pdV and for a perfect gas dU= Cv*dT. I don't really understand why dU= Cv*dT since we have a variation of volume and it is established that dU= Cv*dT when we haven't any modification of the volume. Considering a small variation dV is like constant volume ?
 
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  • #2
There is a difference between how Cv is measured experimentally, and how it is used to solve problems. In a constant volume experiment, the amount of work done is zero, so ΔU=Q. So, to get the change in internal energy as a result of changing only the temperature, we measure the heat added in a constant volume experiment. The heat capacity Cv is defined to be equal to the (∂U/∂T) at constant V. This is how we measure Cv experimentally. However, for an ideal gas, we know that the internal energy U is a function only of T, but not of specific volume V. So we can then use the measured value of Cv from the constant volume experiment to calculate the change in U for any other types of process paths for an ideal gas. For materials other than ideal gases, it isn't valid to assume that the internal energy is independent of specific volume.

Chet
 

1. What is reversible adiabatic expansion?

Reversible adiabatic expansion is a thermodynamic process in which a gas expands without any heat exchange with its surroundings and with no increase in entropy. This process is reversible, meaning that the gas can be compressed back to its original state without any energy loss.

2. How does reversible adiabatic expansion differ from other types of expansion?

Reversible adiabatic expansion differs from other types of expansion, such as isothermal or isochoric expansion, in that it occurs without any heat exchange with the surroundings. This means that the temperature of the gas remains constant during the expansion process.

3. What is the equation for calculating work done during reversible adiabatic expansion?

The equation for calculating work done during reversible adiabatic expansion is W = -nRT[ln(V2/V1)], where n is the number of moles of gas, R is the gas constant, T is the temperature, and V1 and V2 are the initial and final volumes of the gas, respectively.

4. What are some real-life applications of reversible adiabatic expansion?

Reversible adiabatic expansion has many practical applications, such as in the operation of heat engines, refrigeration systems, and gas turbines. It is also used in the production of compressed gases, such as in scuba diving tanks.

5. Is reversible adiabatic expansion an ideal process?

Yes, reversible adiabatic expansion is considered an ideal process in thermodynamics. This means that it does not involve any energy losses and can be reversed without any changes to the surroundings. However, this process is not possible in real life as it requires perfect insulation and infinitely slow expansion.

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