Reaction kinetics for reppe synthesis of propionic acid

In summary, the conversation involves a person seeking help in finding the kinetics of the carbonylation of ethylene to produce propionic acid. They have been searching for a week but have been unsuccessful. The suggested paper by D. J. Smeulders et al. titled "Kinetics and Mechanism of the Carbonylation of Ethylene to Propionic Acid in the Presence of Rhodium Catalysts" is recommended as a good starting point for finding the necessary information. This paper offers detailed kinetic studies on the process, making it a useful resource.
  • #1
ChemEng1234
1
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I need help finding the kinetics(rate laws) of this process. I've been searching for close to a week and can't seem to find them. It the carbonylation of ethylene to produce propionic acid(pretty much any variant of the process will do). I have access to my schools publication library so the name of a paper will suffice.
 
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  • #2
The carbonylation of ethylene to produce propionic acid is a reaction that has been studied in detail. A good starting point for finding the kinetics of this process is the paper by D. J. Smeulders et al., entitled “Kinetics and Mechanism of the Carbonylation of Ethylene to Propionic Acid in the Presence of Rhodium Catalysts” (J. Am. Chem. Soc., 1993, 115, 10, 3917-3925). This paper presents detailed kinetic studies which should provide you with the information you are looking for.
 

What is reaction kinetics?

Reaction kinetics is the study of the rate at which chemical reactions occur, as well as the factors that influence the rate of a reaction.

What is the reppe synthesis of propionic acid?

The reppe synthesis of propionic acid is a chemical reaction used to produce propionic acid from acetylene, carbon monoxide, and water. It is an important industrial process used to produce this carboxylic acid, which is commonly used in food preservation and as a precursor for other chemicals.

What is the mechanism of the reppe synthesis of propionic acid?

The mechanism of the reppe synthesis of propionic acid involves the formation of an intermediate called propionic acid anhydride, which is then hydrolyzed to produce propionic acid. The reaction is catalyzed by a palladium-based catalyst and occurs in multiple steps.

What factors can influence the rate of the reppe synthesis of propionic acid?

The rate of the reppe synthesis of propionic acid can be influenced by several factors, including the concentration of reactants, temperature, pressure, and the presence of a catalyst. These factors can affect the activation energy of the reaction and alter the rate at which the reaction occurs.

What are the applications of propionic acid produced through reppe synthesis?

Propionic acid produced through reppe synthesis has various applications in the food industry as a preservative, in the production of pharmaceuticals, and as a precursor for other chemicals such as esters and polymers. It is also used as a feed additive for livestock and as a component in cosmetics and perfumes.

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