TOF (mass spectrometer) Analyzer Question

In summary, the unknown hydrocarbon ion in the mass spectrometer travels at a speed of 4.7*10^4 m/s in a 0.250 T magnetic field with a radius of curvature of 14.1 cm. This suggests that the ion is pentane with a (q/m) ratio of 1.34*10^6. The formula used to calculate the velocity is v=qBr/m, and the time and curve length can be used to find q/m.
  • #1
carlphysics30
2
0

Homework Statement



An unknown hydrocarbon ion required 9.415*10^-6 seconds to travel through the 0.250 T magnetic field of a mass spectrometer with a radius of curvature of 14.1 cm. Since the magnetic chamber is shaped like a 'D' it only travels half way around the circle.

a. find the speed of the ion through the magnetic field
b. identity of the ion using the charge to mass ratio (q/m)[/B]

Homework Equations



Fm = qvB
Fm=Fnet=Fc
qvB=mv^2/r
Fc=(4π^2/T^2)

Unknown variables: q (charge), m (mass), v (velocity) or V (voltage)[/B]

The Attempt at a Solution



a. Rearranging the formula gives me v=qBr/m. I do not have the (q/m) ratio, so that creates two unknown variables. Next, I tried substituting (4π^2/T^2) as an equivalent for qvB. [/B]

The Fm is 4.453680806*10^11 N.

After this step I am stuck.


ANSWER FROM THE BOOK:
The velocity is 4.7*10^4 m/s, and the substance is pentane, with a (q/m) ratio of 1.34*10^6.
 
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  • #2
You can calculate the curve length the ion travels in the spectrometer, and you know the time. That allows to get the speed.
Afterwards you can find q/m.
 
  • #3
mfb said:
You can calculate the curve length the ion travels in the spectrometer, and you know the time. That allows to get the speed.
Afterwards you can find q/m.

WOW THANKS. I didn't even know it was that simple! thanks again! :)
 

1. What is a TOF Analyzer?

A TOF (time-of-flight) analyzer is an instrument used in mass spectrometry to measure the mass-to-charge ratio (m/z) of ions. It works by accelerating ions through an electric field and measuring the time it takes for them to reach a detector, which can be used to determine their m/z ratio.

2. How does a TOF Analyzer work?

A TOF analyzer works by first ionizing a sample, typically by bombarding it with electrons. The resulting ions are then accelerated through an electric field and into a flight tube. The time it takes for the ions to travel through the flight tube is measured and used to determine their m/z ratio.

3. What are the advantages of using a TOF Analyzer?

TOF analyzers have several advantages over other types of mass spectrometers. They have a wide mass range, high sensitivity, and can be used for both qualitative and quantitative analysis. They also have a fast acquisition speed, making them ideal for high-throughput experiments.

4. What types of samples can be analyzed using a TOF Analyzer?

A TOF analyzer can be used to analyze a wide range of samples, including gases, liquids, and solids. It is commonly used in fields such as proteomics, metabolomics, and environmental analysis to identify and quantify molecules in complex mixtures.

5. What are some common applications of TOF Analyzers?

TOF analyzers have a wide range of applications in various fields of research and industry. They are commonly used for protein identification, drug discovery, environmental analysis, and forensic analysis. They are also used in quality control and process monitoring in pharmaceutical and chemical industries.

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