What does the potential barrier energy measure?

In summary, the energy of an incident charged particle refers to its kinetic energy, while the potential barrier energy refers to the minimum work required to leave a container or object. The barrier height can be quantified by measuring the number of particles that tunnel through it, and it is usually finite in practical containers. This can be seen in the classical analogy of a ball in a bowl, where the barrier is finite even if the sides are leakproof. In terms of potential energy, punching through the walls of a container is equivalent to going over the potential barrier. However, there is no good classical analogy for tunnelling.
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The energy of an incident charged particle refers to its kinetic energy. What does the potential barrier energy refer to qualitatively?

EDIT: Is it just in reference to the "potential barrier" in the classical sense? where if the particle has less than the energy V, then it doesn't go through?

Also, how would one go about quantifying the barrier energy of say, the walls of a container?
 
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Potential energy.
The barrier is part of the potential energy function.

The barrier height of the walls of a container would be the minimum work required to leave the container starting from the potential energy at the bottom.
i.e. to get mass m over a hill height h requires at least mgh work, so the potential barrier height of the hill is mgh.
 
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Usually we design containers that are practically leakproof, so the barrier energy is effectively infinite. But you can quantify the barrier by measuring how many particles tunnel through it and putting it into a tunneling equation.
 
  • #4
We usually make containers so it takes a finite amount of work to remove stuff from them.
This translates to a finite barrier height.

The classical picture of a potential well is something like a ball in a bowl... it rolls back and forth to a height depending on it's energy. Plot the bslls gPE vs horizontal position and you will see the barrier is finite even if the bowl sides are leakproof.
 
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I guess it all depends on the problem at hand. I was picturing a vacuum vessel with gas inside.
 
  • #6
OK. A bottle of gas then...
If you were to describe the container in terms of the potentials that were containing the gas, you would still be describing the amount of work needed to get from one place to another ... because that is what "potential energy" means. If the gas had the kinetic energy to punch through the walls, then it's energy level would be higher than the potential barrier describing the walls.
Punching through the walls, in this case, is the same as going over the potential barrier.

There is no decent classical analogy for tunnelling.
 

1. What is the potential barrier energy?

The potential barrier energy is a measure of the energy required to overcome the repulsive forces between particles in a system. It is commonly used to describe the energy barrier that must be overcome for a reaction to occur or for particles to move through a barrier.

2. How is the potential barrier energy calculated?

The potential barrier energy is calculated using a combination of theoretical models and experimental data. In general, it is determined by measuring the energy differences between reactants and products in a system.

3. What factors affect the potential barrier energy?

The potential barrier energy is influenced by a variety of factors, including the nature of the interacting particles, their distance from each other, and the environment in which they are interacting. Additionally, temperature, pressure, and the presence of catalysts can also affect the potential barrier energy.

4. What is the significance of the potential barrier energy in chemical reactions?

The potential barrier energy plays a crucial role in determining the rate and likelihood of chemical reactions. A higher potential barrier energy means that more energy is required for a reaction to occur, and thus the reaction may be slower or less likely to take place.

5. How can the potential barrier energy be altered or manipulated?

The potential barrier energy can be altered through changes in the conditions of the system, such as temperature, pressure, or the presence of a catalyst. It can also be manipulated through the use of external energy sources, such as heat or light, to provide the necessary energy for a reaction to occur.

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