Ah, that's very interesting!
I never though of using that 100°C boiling point.
so, with that...
Energy to Vaporize = Q = m*l = (2.5e-9 kg)(2.256×106 J/kg) = 5.64e-03 J
and
Q = m*c*delta(t) = (2.5e-9 kg)(4190 J/(kg·K))(67K) = 7.01825e-4 J
adding these two values... Q1 +Q2 = 6.341825e-3 J, which...