Expansion of a point-charge potential

AI Thread Summary
The discussion revolves around the expansion of the point-charge potential using Legendre polynomials, specifically the formula involving r< and r>. The user is struggling to achieve the expected potential curve after including four terms in the expansion. Recommendations include referencing a paper by Carlson and Rushbrooke, which provides correct equations for the expansion. Implementing one of these equations reportedly improved the results. The user is also exploring the behavior of the potential when varying the position of X, noting significant changes in the potential's shape.
Morberticus
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I'm currently trying to manipulate the expansion

\frac{1}{|x_1-x_2|} = \sum_{l=0} \frac{r_{&lt;}^l}{r_{&gt;}^{l+1}}P_{l}\left(cos\left(\gamma\right)\right)

Where r< is the lesser of |x1| and |x2| and P_l are the legendre polynomials.

I have included up to 4 terms and the resultant potential isn't resembling the expected potential curve. Does anyone have any experience with such expansions, or would you recommend a different expansion (I ultimately need it to make a function integrable) ?
 
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Morberticus said:
I'm currently trying to manipulate the expansion

\frac{1}{|x_1-x_2|} = \sum_{l=0} \frac{r_{&lt;}^l}{r_{&gt;}^{l+1}}P_{l}\left(cos\left(\gamma\right)\right)

Where r< is the lesser of |x1| and |x2| and P_l are the legendre polynomials.

I have included up to 4 terms and the resultant potential isn't resembling the expected potential curve. Does anyone have any experience with such expansions, or would you recommend a different expansion (I ultimately need it to make a function integrable) ?


What is the resultant potential you are getting, and what were you expecting? What exactly are you trying to make integrable?
 
Here you go:
Carlson and Rushbrooke, "On the expansion of a coulomb potential in spherical harmonics"
Mathematical Proceedings of the Cambridge Philosophical Society (1950), 46: 626-633
doi:10.1017/S0305004100026190

Equations Ia and Ib give you the correct expansion.
 
alxm said:
Here you go:
Carlson and Rushbrooke, "On the expansion of a coulomb potential in spherical harmonics"
Mathematical Proceedings of the Cambridge Philosophical Society (1950), 46: 626-633
doi:10.1017/S0305004100026190

Equations Ia and Ib give you the correct expansion.

Hi, thanks. I have implemented Ib and it seems to have made an improvement.

gabbagabbahey: When considering |x1-X|^-1: If X is close to the origin and on the z axis, I get a predictable approximation to |x1-X|^-1 (i.e. If I plot the approximate potential across the singularity, I get a finite peak). However, if X is placed further away from the origin, the potential changes, and a caldera forms. I ultimately am constructing plane-wave molecular integrals, so perhaps this isn't even the best approach.
 
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