Affine spaces differ from vector spaces primarily in that they lack a defined origin, meaning points cannot be added or subtracted like vectors. An example of an affine space is a straight line that does not necessarily pass through the origin, while a vector space can be formed by establishing a coordinate system. In R2, points can be associated with vectors originating from the origin, but without a coordinate system, R2 is simply an affine space. The relationship between affine and vector spaces can be understood through translations, where any point in an affine space can be translated to another point, forming a vector that defines the translation. Fixing a point in an affine space creates a correspondence with a vector space, illustrating how affine spaces can be related to vector spaces through the concept of translations.