Voltage is the work done by an electric field when a unit positive charge moves between two points, while potential at a point is the work done to move a charge to a point of zero potential. The relationship between voltage and potential difference is expressed as UAB = UA - UB, indicating that voltage is the negative of potential difference. Electromotive force (emf) refers specifically to the voltage across the terminals of an unloaded voltage source. Understanding these distinctions is crucial for grasping electrical concepts.