About state of matter and melting point

AI Thread Summary
Freezing causes volumetric expansion in water because of the unique structure of ice crystals, which occupy more space than liquid water. When pressure is applied to most solids, their melting points increase due to the increased stability of the solid phase, but ice behaves differently; applying pressure lowers its melting point because it disrupts the crystal structure. Ice has a lower density than water because its molecular arrangement in the solid state creates more open space compared to the denser arrangement of water molecules in the liquid state. The discussion highlights the importance of understanding the molecular structure of ice to explain these phenomena. Overall, the questions emphasize the need for clarity on the behavior of water and ice under different conditions.
songoku
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Homework Statement


Hi all

I have conceptual problems :
1. In cold countries, water in pipe lines freezes in winter season. Freezing causes volumetric expansion and may burst the pipes.
My question :why freezing causes volumetric expansion?


2. Mostly, substance increases their melting point when a pressure is applied in their solid state. Ice is an exception. Applying pressure to ice will lower its melting point.
My question : why when a pressure is applied to an object, the melting point will increase? And why this concept can't be applied to ice?

3. Why does ice has lower density compared to water?

Homework Equations





The Attempt at a Solution


1. I think freezing causes volumetric compression. I imagine the water freezes to ice and I think that the volume becomes smaller.

2. I don't have any ideas.

3. Ice is a solid and I think it should have stronger inter-molecular force compared to water. Stronger inter-molecular force means that it has higher density. But ice floats on water and it means that it has lower density. I don't understand.

Thanks
 
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All of your questions are related to the structure of ice crystals. See http://www.iapws.org/faq1/freeze.htm for an explanation.
 
Last edited by a moderator:
Hi ideasrule

Ah thank a lot for the link. I understand the first and third questions but the link doesn't explain about second question.

Thanks
 
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