I'm not sure I understand your question, but let me try to make the geometric definition of the Euler angles a little more concrete.
Let's start with a globe, and single out three points on the globe:
- The North Pole, which is latitude 90 (north).
- The "West Pole", which is the point on the equator at latitude 0, longitude 0
- The "East Pole", point on the equator at latitude 0, longitude 90 (east)
(nobody calls these points the East Pole or the West Pole, but I'm just using these names to have handy ways to refer to them.)
Let the X axis be the line running from the equator through the West Pole. Let the Y axis be the line running from the equator through the East Pole. Let the Z axis be the line running from the equator through the North Pole. These lines are body-fixed. For some reason, the X-axis is also called the "line of nodes".
Pick three perpendicular (space-fixed) lines that intersect in one point and call them the x-axis, the y-axis and the z-axis. To start with, position the globe so that X axis coincides with the x-axis, the Y axis coincides with the y-axis and the Z axis coincides with the z-axis.
Step 1: Rotate the globe about the Z axis through an angle \alpha. (Positive \alpha means rotating the East Pole toward the West Pole, and negative means rotating away from the West Pole. (\alpha is between +90 and -90, in degrees)
Step 2: Rotate the globe about the (new location of the) X axis through an angle \beta. Note that during this rotation, the line of nodes, which is the X axis, stays fixed. \beta is always positive--it's the angle that the North Pole moves through as it is rotated down toward the x axis. \beta is between 0 and 180 degrees.
Step 3: Rotate the globe again about the (new location of the) Z axis through an angle \gamma. The angle \gamma can be either positive or negative, like \alpha. It's positive if you are rotating the West Pole toward the East Pole, and negative if you are rotating in the opposite direction. Again, \gamma is between 0 and 180.
Now, your question was:
Now, if the body-fixed-XYZ axes are rotated in space, say, about the space-fixed-z axis, How should one define the new nodal line?
The nodal line is the same as the body-fixed X-axis. The idea of the Euler angles is that no matter what the orientation of the X-Y-Z axes are, you can always get that orientation by starting with the X-Y-Z axes lined up with the x-y-z axes and performing the three steps above (for the appropriate choice of \alpha, \beta, \gamma).