Complex conjugate applies only to complex numbers. You don't have the complex conjugate of a ket.
Let me explain this then.
First, as I already said: ##\langle aV |## is the bra associated with the ket ##|aV \rangle##
And, we know that ##|aV \rangle = a |V \rangle##.
Then, we know from your original post that the bra associated with ##a |V \rangle## is ##\langle V|a^*##.
Putting this all together we have: ##\langle aV | = \langle V|a^*##
Note that bras and kets are intended to form the inner product, which in QM is linear in the second argument. In other words we have:
$$\langle V|aU \rangle = a \langle V|U \rangle \ \text{and} \ \langle aV|U \rangle = a^* \langle V|U \rangle$$
And that's another reason that when you take a complex scalar outside of a bra you get its complex conjugate.