Because the reciprocal of a cardinal has no meaning here...
The probability of an event A occurring is defined by a measure function, which essentially is a way of measuring the area that A occupies with respect to W. The measure function is defined to take a real value between [0,1], you could pick other measure functions but then you're not following the definition of a probability.
One standard example is if you have the interval [0,1] and you pick a number at random, what is the probability that you pick a rational number?
We define the probability of picking a number inside of an interval (a,b) as b-a (and as [0,1] has length 1 we see this defines a probability). Then since the rationals are countable, we can list them q_1, q_2,... and around q_i we can construct an interval of length \frac{e}{2^n} for any e>0. Then adding up all the lengths of the intervals gives us at least the probability that we pick a number inside one of those intervals (if there's overlap, then we overestimated, but that's OK). We have geometric series, so this comes out to a total probability of e. But e was arbitrary, so the probability of picking a rational number < e for all e>0, so it must be zero. Hence the probability of picking an irrational number is 1.
So while it is possible that you pick a rational number, the probability is 0. A possible interpretation in practical terms is that even if you keep picking numbers at random, your chance of picking a rational number never increases, whereas if the probability was anything other than 0, your chance of eventually picking one would increase to 1 as you make more picks
As an aside, notice that Q is dense in R but the probability was 0, not 1. Knowing a set is dense doesn't tell you anything about its probability