Are there phonons in a free electron gas?

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Discussion Overview

The discussion centers around the existence of phonons in a free electron gas, particularly in the context of thermodynamic properties and potential applications such as a Carnot engine. Participants explore whether phonons can emit and absorb thermal energy in an electron gas without an underlying lattice, and the implications of this for efficiency in thermodynamic cycles.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation

Main Points Raised

  • The original poster (OP) questions whether phonons can exist in a confined electron gas and suggests that a separate system of phonons may carry thermal energy, leading to above-Carnot efficiencies.
  • Some participants argue that the light observed may be due to traveling photons, although this is noted as a misunderstanding of the OP's question regarding phonons.
  • One participant clarifies that while an electron gas can support sound waves, it is charged and thus includes electric field effects, leading to oscillations known as plasma oscillations rather than phonons.
  • Another participant asserts that a gas of this type would support plasmons instead of phonons.
  • There is a discussion about whether plasmons can carry thermal energy, with one participant noting that while it is theoretically possible, the typical energies of plasmons are much higher than thermal energies at ambient temperature, making excitation unlikely without specific conditions.

Areas of Agreement / Disagreement

Participants generally agree that phonons do not exist in a free electron gas and that plasmons are the relevant excitations. However, there is no consensus on the implications for thermal energy transfer and the feasibility of achieving above-Carnot efficiencies.

Contextual Notes

There are unresolved assumptions regarding the behavior of phonons and plasmons in the context of thermodynamics and the specific conditions under which they might carry thermal energy.

bjnartowt
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TL;DR
Is there emission and absorption of phonons within an electron gas lacking an underlying lattice?
It is well-known that the electron gas of volume V has an equation of state p=p(V) and thus has a bulk modulus $$B=-V(dp/dV)$$. Suppose the electron gas had no underlying lattice but was confined. Do phonons emit and absorb in such an electron gas at finite temperature?

The reason I ask is because I have found that if I try to make a Carnot engine with an electron gas as the working fluid, I get above-Carnot efficiencies if I consider the electrons alone to carry thermal energy. I can only conclude that a separate system of phonons exists within the electrons that carry thermal energy.

Comments?
 
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My guess is that the light one might see is from traveling photons. I am unaware of photon energy being held in captivity. I may be very wrong but that’s the extent of my knowledge.

I must have bad eyes or a bad brain or both.
 
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lsume said:
My guess is that the light one might see is from traveling photons. I am unaware of photon energy being held in captivity. I may be very wrong but that’s the extent of my knowledge.

The OP is asking about PHONONS, not PHOTONS. It is why this is the Condensed Matter forum.

Zz.
 
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It would appear that an electron gas would support sound wave, just like an ordinary gas, however, the electron gas is charged. So in addition to gas pressure, you have to include electric field effects. Therefore, the oscillation of electron gas do exist but they are known as plasma oscillation.
bjnartowt said:
Summary: Is there emission and absorption of phonons within an electron gas lacking an underlying lattice?

I get above-Carnot efficiencies
That, according to the sate of thermodynamics, is impossible. You can derive Carnot cycle efficiency without any reference to any physical system. All you need is the concept of energy and entropy.
 
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Indeed, a gas of that type would support plasmons (not phonons).
 
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f95toli said:
Indeed, a gas of that type would support plasmons (not phonons).

Incidentally, in low-dimensional cases, these plasmons afford us a nice description when the Fermi liquid renormalisation scheme stops working, as a highly correlated 1D electron liquid can be described as a gas of non-interacting plasmons.
 
Thank you all for your replies.

My next question is, naturally, if plasmons can carry thermal energy.
 
bjnartowt said:
My next question is, naturally, if plasmons can carry thermal energy
In principle yes, however, typical plasmon energies are in a few eV range that is much larger than kT at ambient temperature (~ 0.025 eV), so probability of plasmon excitation at ambient temperature is very low.
To get some contribution you have to either increase the temperature or lower plasmon frequency (this by lowering plasma density).
 
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