Atomic Energy Levels - Calculating the Minimum Energy of Light Emitted

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SUMMARY

The discussion focuses on calculating the longest wavelength of light emitted from an atom using the formula λ = hc/E. The minimum energy of the emitted light is determined to be E_min = 2.1 eV, leading to a maximum wavelength of approximately λ_max = 5.91 × 10^-7 m. A participant raises a question regarding the energy difference between the ionization level and n=4, noting it is smaller than 2.1 eV. The response clarifies that a transition is necessary for photon emission, emphasizing the importance of energy levels in calculating emitted light.

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  • Understanding of quantum mechanics and atomic structure
  • Familiarity with the equation λ = hc/E
  • Knowledge of electron energy levels in atoms
  • Basic principles of photon emission and transitions
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Homework Statement


attachment.php?attachmentid=51788&stc=1&d=1349951739.jpg

Determine the longest wavelength of light emitted from this atom.

Homework Equations


\lambda=\frac{hc}{E}


The Attempt at a Solution


I calculated the lowest energy of the light emitted: E_{min}=2.1(eV)
Then the longest wavelength would be: \lambda_{max}=\frac{hc}{E_{min}}=\frac{4.14×10^{-15}×3×10^{8}}{2.1}≈5.91×10^{-7}(m)

What confused me is the energy difference between the ionization level and n=4 is even smaller than 2.1 eV: 1.6-0=1.6(eV). Am I going to take this energy difference as the minimum energy emitted? Also, can you please point out if the way I take the absolute value of the energy levels and subtract them is correct?

Thank you very much.
LovePhys
 

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A transition is necessary for a photon to be emitted. If the energy of an electron is raised to the 0 eV level it will be free of the atom and will not be available for further transitions. The energy of the photon as it transist from the upper energy level to the lower is Eupper - Elower so the two negatives makes the lower energy value positive.
 
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