Atomic Layer Deposition Reactor Design?

Click For Summary
SUMMARY

The discussion focuses on the materials used in Atomic Layer Deposition (ALD) reactors, specifically questioning whether quartz or metals like stainless steel and aluminum are appropriate for reactors utilizing gaseous precursors. It is established that quartz tubes are commonly used, particularly in chemical vapor deposition (CVD) processes, while metal reactors are typically associated with molecular beam epitaxy (MBE). The choice of reactor material may depend on the specific reactants involved, such as atomic hydrogen, and the potential reactivity of materials like fluorides with quartz. Historical references indicate that metal chambers may have been used in older systems, but quartz remains prevalent in modern applications.

PREREQUISITES
  • Understanding of Atomic Layer Deposition (ALD) principles
  • Familiarity with Chemical Vapor Deposition (CVD) techniques
  • Knowledge of materials science, particularly regarding reactor materials
  • Awareness of the implications of reactant choice on reactor design
NEXT STEPS
  • Research the properties and applications of quartz and fused silica in CVD reactors
  • Explore the differences between molecular beam epitaxy (MBE) and chemical vapor deposition (CVD)
  • Investigate the effects of various reactants, such as atomic hydrogen and fluorides, on reactor materials
  • Review historical advancements in ALD reactor designs and materials used over the past decades
USEFUL FOR

This discussion is beneficial for materials scientists, chemical engineers, and professionals involved in the design and optimization of Atomic Layer Deposition reactors, particularly those focused on the choice of reactor materials and their implications on process efficiency.

SupaVillain
Messages
47
Reaction score
2
Is it made of quartz or stainless steel/aluminum or what? Does it matter which?that's all I need to know, I just can't seem to find if they can be made of standard vacuum metals or if they have to be quartz. Only really seen some diagrams mention quartz tubes but the pictures of large ones seem to be a large (grocery cart size) metal sphere reactor
 
Engineering news on Phys.org
I see now that there's ones that work off of molecular beam epitaxy and ones that work off of gaseous precursors in the range of millitorr. I am asking about the one that uses gaseous precursors, NOT MBE, as I already know that method is with a large stainless or aluminum reactor
 
The answer may depend on the reactants, e.g., atomic hydrogen.

Some examples:

Quartz tube reactor
http://www.dtic.mil/dtic/tr/fulltext/u2/a250607.pdf

Proceedings of the Third International Symposium on Diamond Materials - look for fused silica or pyrex.

http://encyclopedia.che.engin.umich.edu/Pages/Reactors/CVDReactors/CVDReactors.html

http://www.ewp.rpi.edu/hartford/users/papers/engr/ernesto/morens/EP/References/CVD%20Processes%20and%20Equipment.pdf (seem to be mostly quartz or fused silica)

I'd have to dig deep in my archives to find some examples from 30+ years ago to see if any where metal chambers. I do remember some plasma vapor deposition systems, but I don't recall the reaction chamber material. It may be the graphite or Mo were used for certain applications, but it's been decades since I looked at various processes.

I would think that fluorides or HF would be problematic in quartz or silica systems.
 
Last edited by a moderator:

Similar threads

Replies
1
Views
1K
  • · Replies 3 ·
Replies
3
Views
4K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 10 ·
Replies
10
Views
10K
  • · Replies 1 ·
Replies
1
Views
4K
Replies
4
Views
2K
Replies
3
Views
2K
  • · Replies 6 ·
Replies
6
Views
4K
  • · Replies 19 ·
Replies
19
Views
5K