The discussion centers on calculating the first and second-order diffraction angles for X-rays diffracted by a crystal with atomic plane spacing of 0.120 nm and energy of 15.0 keV. It highlights the use of the formula 2dcosΘ = mλ instead of the more commonly known 2dsinΘ = mλ, emphasizing that the angle in question is between the crystal surface and the diffracted beams rather than the normal to the surface. This distinction is crucial because Bragg diffraction involves reflection of X-rays from the crystal surface, unlike typical light diffraction that involves transmission. The manual's approach is clarified as being appropriate for the specific context of Bragg diffraction. Understanding these angles and the correct formula is essential for accurate calculations in crystallography.