Buckyball encased uranium - the smallest possible pebble bed

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The discussion explores the feasibility of using smaller pebble sizes in pebble bed reactors, specifically considering the concept of encasing a uranium atom within a carbon buckyball. While theoretically possible, concerns arise regarding the structural integrity of the fullerene during fission, as the energy release could exceed the bond strength of the carbon shell. The practicality of such "buckynuke" fuel is questioned due to potential fabrication costs and the likelihood of the carbon structure failing during fission, leading to the release of fragments and fission products. Additionally, the role of the carbon shell as a moderator is debated, with uncertainty about whether it would effectively slow down thermal neutrons or hinder their interaction with the uranium. Overall, while intriguing as a thought experiment, the concept faces significant practical and theoretical challenges.
Jeremy Thomson
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Is there a trend in pebble bed reactors towards smaller pebble sizes? The smallest conceivable would be a carbon buckyball encasing a (single?) uranium atom. This Wikipedia article (https://en.wikipedia.org/wiki/Endohedral_fullerene) says two cerium atoms have been encapsulated in a c80 buckyball. So I guess there's enough room inside an arbitrarily large carbon fullerene for a uranium atom. I have no idea if this is actually possible. If fission were to occur would the fullerene necessarily split apart? I believe they are quite stretchy, of course fission is an enormous energy release. I just don't know the strength of c80 vs the energy of fission. I can't envisage buckynuke fuel being at all practical, most likely too expensive to fabricate. You'd need have some separator (piping) for coolant. Most likely the fullerene wouldn't survive fission so graphene fragments and loose fission products making mischief. But as a thought experiment would the carbon shell act well as a moderator? Or would the carbon shell act to protect the uranium from thermal neutrons, by bouncing neutrons away from the encapsulated uranium?
 
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Encasing one U atom in a shell of ~80 C atoms would make for a low fuel (U) to moderator (C) ratio.

Atomic bonds have energies on the order of eV, whereas the combined kinetic energy of the fission products is on the order of 168 MeV.
 
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