To calculate the molecular weight of Al2(SO4)3·14.3H2O, one must consider the average of 14.3 water molecules per formula unit, which translates to 28.6 hydrogen atoms and 14.3 oxygen atoms. The discussion clarifies that while water molecules are typically whole numbers, the average can be fractional in certain contexts. Participants confirm that the breakdown of elements includes 2 aluminum, 3 sulfur, and the calculated hydrogen and oxygen from the water. The final molecular weight calculation should integrate these values accurately. Understanding the average number of water molecules is crucial for precise molecular weight determination.